{"title":"三乙基硼烷诱导烯烃与三-2-呋喃日耳曼的加氢化反应","authors":"Tomoaki Nakamura, Shinobu Tanaka, Hideki Yorimitsu, Hiroshi Shinokubo, Koichiro Oshima","doi":"10.1016/S1387-1609(01)01248-8","DOIUrl":null,"url":null,"abstract":"<div><p>Tri-2-furylgermane in the presence of a catalytic amount of triethylborane adds to internal alkenes as well as to terminal alkenes effectively, giving the corresponding adducts in good to excellent yields. The addition of tri-2-furylgermane to silyl enol ethers followed by elimination of germyl and siloxy moieties provides a new route for the conversion of ketones into alkenes.</p></div>","PeriodicalId":100305,"journal":{"name":"Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry","volume":"4 6","pages":"Pages 461-470"},"PeriodicalIF":0.0000,"publicationDate":"2001-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1387-1609(01)01248-8","citationCount":"1","resultStr":"{\"title\":\"Triethylborane-induced hydrogermylation of alkenes with tri-2-furylgermane\",\"authors\":\"Tomoaki Nakamura, Shinobu Tanaka, Hideki Yorimitsu, Hiroshi Shinokubo, Koichiro Oshima\",\"doi\":\"10.1016/S1387-1609(01)01248-8\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Tri-2-furylgermane in the presence of a catalytic amount of triethylborane adds to internal alkenes as well as to terminal alkenes effectively, giving the corresponding adducts in good to excellent yields. The addition of tri-2-furylgermane to silyl enol ethers followed by elimination of germyl and siloxy moieties provides a new route for the conversion of ketones into alkenes.</p></div>\",\"PeriodicalId\":100305,\"journal\":{\"name\":\"Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry\",\"volume\":\"4 6\",\"pages\":\"Pages 461-470\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2001-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S1387-1609(01)01248-8\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1387160901012488\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1387160901012488","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Triethylborane-induced hydrogermylation of alkenes with tri-2-furylgermane
Tri-2-furylgermane in the presence of a catalytic amount of triethylborane adds to internal alkenes as well as to terminal alkenes effectively, giving the corresponding adducts in good to excellent yields. The addition of tri-2-furylgermane to silyl enol ethers followed by elimination of germyl and siloxy moieties provides a new route for the conversion of ketones into alkenes.
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