{"title":"碱金属卤化物晶格的连续介质模型的离子半径","authors":"D. Rosseinsky","doi":"10.1039/J19710000608","DOIUrl":null,"url":null,"abstract":"Application of a long-advocated sphere-in-continuum model to MX lattices yields halide radii in good agreement with those actually observed in diffraction studies. Not only do the mean values agree, but observed fluctuations from constancy are reflected in the individual values calculated for each MX, a second-order effect.","PeriodicalId":17321,"journal":{"name":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Ionic radii from a continuum model for alkali-metal halide lattices\",\"authors\":\"D. Rosseinsky\",\"doi\":\"10.1039/J19710000608\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Application of a long-advocated sphere-in-continuum model to MX lattices yields halide radii in good agreement with those actually observed in diffraction studies. Not only do the mean values agree, but observed fluctuations from constancy are reflected in the individual values calculated for each MX, a second-order effect.\",\"PeriodicalId\":17321,\"journal\":{\"name\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J19710000608\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J19710000608","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Ionic radii from a continuum model for alkali-metal halide lattices
Application of a long-advocated sphere-in-continuum model to MX lattices yields halide radii in good agreement with those actually observed in diffraction studies. Not only do the mean values agree, but observed fluctuations from constancy are reflected in the individual values calculated for each MX, a second-order effect.
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