{"title":"4-硅基溴苯与苯硼酸在热和微波条件下的Suzuki-Miyaura反应","authors":"I. Greiner, E. Hohmann, L. Vida, G. Keglevich","doi":"10.2174/1874095200801020065","DOIUrl":null,"url":null,"abstract":"The coupling reaction of phenylboronic acid with 4-silyl-bromobenzenes incorporating an ionic liquid support or its neutral analogue at 80 °C in DMF/H2O in the presence of Pd(PPh3)4 and Na2CO3 takes place much faster and more efficiently under microwave irradiation than under traditional heating. It is an attractive method to carry out the generally slow Suzuki-Miyaura reactions under microwave conditions.","PeriodicalId":23020,"journal":{"name":"The Open Organic Chemistry Journal","volume":"40 1","pages":"65-67"},"PeriodicalIF":0.0000,"publicationDate":"2008-06-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Suzuki-Miyaura Reaction of 4-Silyl-bromobenzenes with Phenylboronic Acid under Thermal and Microwave Conditions\",\"authors\":\"I. Greiner, E. Hohmann, L. Vida, G. Keglevich\",\"doi\":\"10.2174/1874095200801020065\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The coupling reaction of phenylboronic acid with 4-silyl-bromobenzenes incorporating an ionic liquid support or its neutral analogue at 80 °C in DMF/H2O in the presence of Pd(PPh3)4 and Na2CO3 takes place much faster and more efficiently under microwave irradiation than under traditional heating. It is an attractive method to carry out the generally slow Suzuki-Miyaura reactions under microwave conditions.\",\"PeriodicalId\":23020,\"journal\":{\"name\":\"The Open Organic Chemistry Journal\",\"volume\":\"40 1\",\"pages\":\"65-67\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2008-06-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"The Open Organic Chemistry Journal\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2174/1874095200801020065\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"The Open Organic Chemistry Journal","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2174/1874095200801020065","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Suzuki-Miyaura Reaction of 4-Silyl-bromobenzenes with Phenylboronic Acid under Thermal and Microwave Conditions
The coupling reaction of phenylboronic acid with 4-silyl-bromobenzenes incorporating an ionic liquid support or its neutral analogue at 80 °C in DMF/H2O in the presence of Pd(PPh3)4 and Na2CO3 takes place much faster and more efficiently under microwave irradiation than under traditional heating. It is an attractive method to carry out the generally slow Suzuki-Miyaura reactions under microwave conditions.
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