应力作用下奥氏体不锈钢焊接区腐蚀行为的研究

Y. Youssef, Po Box Abu Kir Alexandria Egypt Maritime Transport, Walaa El Bestawy, M. Ghazy, M. Shehadeh, I. Hassan
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引用次数: 2

摘要

研究了奥氏体不锈钢在静态和动态条件下的腐蚀行为。研究了焊接和未焊接奥氏体不锈钢SS304、SS310、SS316在三种不同搅拌速度下的腐蚀行为;转速分别为100、200、350两种不同的腐蚀环境;海水(3.5% NaCl),酸性氯化铁(FeClᴣ)。用分光光度法测定腐蚀速率。用光学显微镜观察其微观结构。实验结果表明,酸性氯化铁的腐蚀速率最高,为8.56 mg。SS304在350 rpm转速下(高机械应力条件下),与相同条件下的海水相比,7.96×10 -4 mg。最小-1厘米-2。由于焊接区和热影响区(HAZ)的热应力增大,不锈钢焊区对腐蚀环境高度敏感。此外,由于搅拌速度对传质和机械应力的影响,腐蚀速率随搅拌速度的增加而增加。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Investigation of the Corrosion Behaviour of Welded Area of Austenitic Stainless Steels under Stress
The corrosion behavior of austenitic stainless steel was investigated under both static and dynamic conditions. In this study, corrosion behavior of welded and unwelded austenitic stainless steels, SS304, SS310, SS316 were investigated using three different stirring speeds; 100, 200, 350 rpm and were subjected to two different corrosive environments; seawater (3.5% NaCl), and acidic ferric chloride (FeClᴣ). The rate of corrosion was measured using spectrophotometry. The microstructure was examined using optical microscopy. Experimental results indicated that the highest corrosion rate was observed in acidic ferric chloride, 8.56 mg. min -1 .cm -2 for SS304 at 350 rpm speed (high mechanical stress condition), compared to seawater under the same conditions, 7.96×10 -4 mg. min -1 .cm -2 . Welded stainless steel area were highly sensitive to the corrosive environment as a result of the increasing thermal stresses in both the weld zone and the heat affected zone (HAZ). Also, the corrosion rate was found to increase with increasing the stirring speed due to its effect on the mass transfer and mechanical stresses.
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