丁基化羟基甲苯(bht)对回收高密度聚乙烯(hfpe)塑料垃圾土工膜物理性能的影响

Veren Fransiska, Intan Syahbanu, Adhitiyawarman Adhitiyawarman
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摘要

利用再生高密度聚乙烯(HDPE)制备土工膜建筑材料。本研究的目的是研究添加丁基羟基甲苯(BHT)作为抗氧化剂对土工膜性能的影响。利用傅里叶变换红外光谱(FTIR)分析了HDPE再生膜和土工膜的官能团。通过观察土工膜的力学性能、透气性和疏水性,确定了最佳的BHT添加量。FTIR分析结果表明,再生HDPE在2912和2847 cm-1波长处存在官能团(C-H拉伸);1474和1467 cm-1 (CH2弯曲);721 cm-1 (CH2 Rock)。与其他材料配制得到土工膜后,没有发现新的峰,说明BHT在土工膜中只发生了物理相互作用。所有土工膜都不透水,疏水性达到100%。土工膜在BHT添加量为0.25 b/b%时的拉伸试验值最高,埋前和埋后4周的拉伸试验值分别为21.235 MPa和16.01 MPa。这可能是由于低浓度的BHT(极性较低)与非极性的HDPE(相容性较好)之间的相互作用
本文章由计算机程序翻译,如有差异,请以英文原文为准。
THE EFFECT OF ADDITION BY BUTHYLATED HYDROXYTOLUENE (BHT) ON PHYSICAL PROPERTIES OF GEOMEMBRANE FROM RECYCLED HIGH DENSTY POLYETHYLENE (HFPE) PLASTIC WASTE
Recycled High Density Polyethylene (HDPE) has been prepared for geomembrane construction material. The aim of this research was to study the effect of Butylated Hydroxytoluene (BHT) addition as an antioxidant on the characteristics of the resulting geomembrane. Fourier Transform Infra Red (FTIR) analysis was carried out to examine functional groups of recycled HDPE and prepared geomembranes. Mechanical properties, permeability and hydrophobicity of geomembrane were observed to determined optimum BHT addition. The results of FTIR analysis on recycled HDPE showed the presence of functional groups at wavelengths 2912 and 2847 cm-1 (C-H stretching); 1474 and 1467 cm-1 (CH2 bend); 721 cm-1 (CH2 Rock). After being formulated with other materials to obtain geomembranes, it was not found new peak indicating that the presence of BHT in geomembrane only physical interaction occurs. All of geomembranes had no permeability to water and reach 100% of hydrophobicity. The highest­ tensile test value was shown by geomembrane with 0,25 b/b% of BHT which about 21.235 MPa and 16.01 MPa for before and after soil burial test for four weeks, respectively. Perhaps might be due to the interaction between BHT at low concentrations which has lower polarity and HDPE which is nonpolar has better compatibility than at other concentrations
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