{"title":"含氮配体钯络合加氢催化剂对催化毒物的抗性","authors":"A.V. Novikova, G.M. Cherkashin, A.I. El'natanova (dec.), Ye.Ya. Mirskaya, O.P. Parenago, V.M. Frolov","doi":"10.1016/0031-6458(89)90101-9","DOIUrl":null,"url":null,"abstract":"<div><p></p><ul><li><span>1.</span><span><p>1. Supported palladium complex catalysts for selective hydrogenation of dienes and acetylenes, containing higher aliphatic amines as ligands, possess comparatively high resistance to attack by different catalytic poisons.</p></span></li><li><span>2.</span><span><p>2. On the basis of the data obtained, the inhibitors investigated can be placed in the following order of strength of poisoning: <span><math><mtext>CO</mtext><mtext>≫</mtext><mtext>RSH</mtext><mtext>></mtext><mtext>R</mtext><msub><mi></mi><mn>2</mn></msub><mtext>S</mtext><mtext>></mtext><mtext>PPh</mtext><msub><mi></mi><mn>3</mn></msub><mtext>⋟</mtext><mtext>thiophene</mtext><mtext>></mtext><mtext>oxygen</mtext><mtext>></mtext><mtext>water</mtext></math></span>.</p></span></li></ul></div>","PeriodicalId":19738,"journal":{"name":"Petroleum Chemistry U.s.s.r.","volume":"29 2","pages":"Pages 108-114"},"PeriodicalIF":0.0000,"publicationDate":"1989-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0031-6458(89)90101-9","citationCount":"0","resultStr":"{\"title\":\"Resistance of palladium complex hydrogenation catalysts with nitrogen-containing ligands to attack by catalytic poisons\",\"authors\":\"A.V. Novikova, G.M. Cherkashin, A.I. El'natanova (dec.), Ye.Ya. Mirskaya, O.P. Parenago, V.M. Frolov\",\"doi\":\"10.1016/0031-6458(89)90101-9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p></p><ul><li><span>1.</span><span><p>1. Supported palladium complex catalysts for selective hydrogenation of dienes and acetylenes, containing higher aliphatic amines as ligands, possess comparatively high resistance to attack by different catalytic poisons.</p></span></li><li><span>2.</span><span><p>2. On the basis of the data obtained, the inhibitors investigated can be placed in the following order of strength of poisoning: <span><math><mtext>CO</mtext><mtext>≫</mtext><mtext>RSH</mtext><mtext>></mtext><mtext>R</mtext><msub><mi></mi><mn>2</mn></msub><mtext>S</mtext><mtext>></mtext><mtext>PPh</mtext><msub><mi></mi><mn>3</mn></msub><mtext>⋟</mtext><mtext>thiophene</mtext><mtext>></mtext><mtext>oxygen</mtext><mtext>></mtext><mtext>water</mtext></math></span>.</p></span></li></ul></div>\",\"PeriodicalId\":19738,\"journal\":{\"name\":\"Petroleum Chemistry U.s.s.r.\",\"volume\":\"29 2\",\"pages\":\"Pages 108-114\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1989-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0031-6458(89)90101-9\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Petroleum Chemistry U.s.s.r.\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0031645889901019\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Petroleum Chemistry U.s.s.r.","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0031645889901019","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Resistance of palladium complex hydrogenation catalysts with nitrogen-containing ligands to attack by catalytic poisons
1.
1. Supported palladium complex catalysts for selective hydrogenation of dienes and acetylenes, containing higher aliphatic amines as ligands, possess comparatively high resistance to attack by different catalytic poisons.
2.
2. On the basis of the data obtained, the inhibitors investigated can be placed in the following order of strength of poisoning: .
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