氨乙醇摩尔比对纳米二氧化硅吸附罗丹明b染料的影响

Yayuk Puji Lestari, Amaria Amaria
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引用次数: 1

摘要

采用不同的氨乙醇摩尔比成功地合成了吸附罗丹明B的二氧化硅纳米颗粒。本研究旨在确定不同氨乙醇摩尔比下吸附剂的特性、pH下的最大吸附量和接触时间。从稻壳灰中提取Na2SiO3,合成氨乙醇摩尔比(14:1,21:1,28:1和42:1)的吸附剂,并对其进行表征。在吸附剂中研究的参数包括官能团、粒径、最大pH值和吸附速率常数。FTIR结果表明,所有吸附剂都有官能团,表明二氧化硅的存在。结果表明,NS 14:1的最佳摩尔比为39.82 nm。NS 14:1对罗丹明B的最佳吸附条件为pH = 0.00419 mmol。n: 14:1吸附速率常数为102.42 g.mmol-1。Min-1遵循伪二级动力学模型。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
EFFECT OF AMMONIA-ETHANOL MOLE RATIO ON THE SILICA NANOPARTICLES SYNTHESIZED FOR RHODAMINE B DYES ADSORPTION
Various ammonia-ethanol mole ratios were successfully used for the synthesis of silica nanoparticles for rhodamine B adsorption. This study aims to determine the characteristics of the adsorbent at different ammonia-ethanol mole ratios, maximum adsorption at pH, and contact time. Several steps, including extraction of Na2SiO3 from rice husk ash, synthesis of adsorbents with ammonia-ethanol mole ratios (14:1, 21:1, 28:1, and 42:1), and their characterization. The parameters studied in the adsorbent include the functional groups, particle size, maximum pH, and rate constant adsorption. The FTIR results showed that all adsorbents had functional groups, indicating the presence of silica. The results suggest that the optimum mole ratio of NS 14:1 particles has a size of 39.82 nm. The optimum adsorption of rhodamine B by NS 14:1 occurred at a pH 3 of 0.00419 mmol.g-1 and a contact time of 40 min. The rate constant of adsorption by NS 14:1 was 102.42 g.mmol-1.min-1 followed a pseudo-second order kinetic model.
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