H. Guerrero, Félix M. Royo, C. Lafuente
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Volumetric Study of the Binary Mixtures Containing a Branched Hexane and an Isomeric Chlorobutane
This paper reports densities at atmospheric pressure and at three temperatures T = (283.15, 298.15, and 313.15) K of eight binary mixtures involving a branched hexane (3-methylpentane or 2,2-dimethylbutane) and each one of the isomeric chlorobutanes (1-chlorobutane, 2-chlorobutane, 1-chloro-2-methylpropane or 2-chloro-2-methylpropane). Excess volumes were calculated from experimental densities and correlated with the Redlich-Kister equation. Moreover, the excess volumes were analysed using the Prigogine-Flory-Patterson theory.
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