阳离子开环聚合的定制聚合物

E. Goethals, P. Caeter, J. Geeraert, F. D. Prez
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引用次数: 9

摘要

在对阳离子开环聚合(CROP’s)按其聚合机理进行一般分类后,提出了一些基于CROP的定制聚合物的例子。用于合成这些定制结构的单体有四氢呋喃(THF)、n -叔丁基叠氮啶(TBA)、2-甲基-1,3-恶唑啉(MeOX)和1,3-二恶唑烷(DXL)。聚合物结构包括不同的嵌段和接枝共聚物、高分子单体、星形聚合物、聚合物网络和互穿聚合物网络(ipn)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Tailored polymers by cationic ring‐opening polymerization
After a general classification of the cationic ring-opening polymerizations (CROP's) according to their polymerization mechanism, a number of examples of tailored polymers based on CROP are presented. The monomers used for the synthesis of these tailored structures are tetrahydrofuran (THF), N-tert-butyl aziridine (TBA), 2-methyl-1,3-oxazoline (MeOX) and 1,3-dioxolane (DXL). The polymer structures include different block and graft copolymers, macromonomers, star-shaped polymers, polymer networks and interpenetrating polymer networks (IPNs)
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