{"title":"扭弯向列液晶的微晶流变性和伪层压缩弹性常数","authors":"M. P. Kumar, P. Kula, S. Dhara","doi":"10.1103/PHYSREVMATERIALS.4.115601","DOIUrl":null,"url":null,"abstract":"In twist-bend nematic (N\\textsubscript{TB}) liquid crystals (LCs), the mean molecular orientation exhibits heliconical structure with nanoscale periodicity. On the mesoscopic scale, N\\textsubscript{TB} resembles layered systems (like smectics), where the helical pitch is equivalent to \"pseudo-layers\" without a true mass density wave. We study rheological properties of a N\\textsubscript{TB} phase and compare the results with those of an usual SmA phase. Analysing the shear response and adapting a simplified physical model for rheology of defect mediated lamellar systems we measure the pseudo-layer compression elastic constant $B_{eff}$ of N\\textsubscript{TB} phase from the measurements of dynamic modulus $G^{*}(\\omega)$. We find that $B_{eff}$ of the N\\textsubscript{TB} phase is in the range of $10^{3}-10^{6}$ Pa and it follows a temperature dependence, $B_{eff}\\sim (T_{TB}-T)^{2}$ as predicted by the recent coarse-grained elastic theory. Our results show that the structural rheology of N\\textsubscript{TB} is strikingly similar to that of the usual smectic LCs although the temperature dependence of $B_{eff}$ is much faster than smectic LCs as predicted by the coarse-grained models.","PeriodicalId":8472,"journal":{"name":"arXiv: Soft Condensed Matter","volume":"23 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2020-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"Smecticlike rheology and pseudolayer compression elastic constant of a twist-bend nematic liquid crystal\",\"authors\":\"M. P. Kumar, P. Kula, S. Dhara\",\"doi\":\"10.1103/PHYSREVMATERIALS.4.115601\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In twist-bend nematic (N\\\\textsubscript{TB}) liquid crystals (LCs), the mean molecular orientation exhibits heliconical structure with nanoscale periodicity. On the mesoscopic scale, N\\\\textsubscript{TB} resembles layered systems (like smectics), where the helical pitch is equivalent to \\\"pseudo-layers\\\" without a true mass density wave. We study rheological properties of a N\\\\textsubscript{TB} phase and compare the results with those of an usual SmA phase. Analysing the shear response and adapting a simplified physical model for rheology of defect mediated lamellar systems we measure the pseudo-layer compression elastic constant $B_{eff}$ of N\\\\textsubscript{TB} phase from the measurements of dynamic modulus $G^{*}(\\\\omega)$. We find that $B_{eff}$ of the N\\\\textsubscript{TB} phase is in the range of $10^{3}-10^{6}$ Pa and it follows a temperature dependence, $B_{eff}\\\\sim (T_{TB}-T)^{2}$ as predicted by the recent coarse-grained elastic theory. Our results show that the structural rheology of N\\\\textsubscript{TB} is strikingly similar to that of the usual smectic LCs although the temperature dependence of $B_{eff}$ is much faster than smectic LCs as predicted by the coarse-grained models.\",\"PeriodicalId\":8472,\"journal\":{\"name\":\"arXiv: Soft Condensed Matter\",\"volume\":\"23 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2020-08-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"arXiv: Soft Condensed Matter\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1103/PHYSREVMATERIALS.4.115601\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"arXiv: Soft Condensed Matter","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1103/PHYSREVMATERIALS.4.115601","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Smecticlike rheology and pseudolayer compression elastic constant of a twist-bend nematic liquid crystal
In twist-bend nematic (N\textsubscript{TB}) liquid crystals (LCs), the mean molecular orientation exhibits heliconical structure with nanoscale periodicity. On the mesoscopic scale, N\textsubscript{TB} resembles layered systems (like smectics), where the helical pitch is equivalent to "pseudo-layers" without a true mass density wave. We study rheological properties of a N\textsubscript{TB} phase and compare the results with those of an usual SmA phase. Analysing the shear response and adapting a simplified physical model for rheology of defect mediated lamellar systems we measure the pseudo-layer compression elastic constant $B_{eff}$ of N\textsubscript{TB} phase from the measurements of dynamic modulus $G^{*}(\omega)$. We find that $B_{eff}$ of the N\textsubscript{TB} phase is in the range of $10^{3}-10^{6}$ Pa and it follows a temperature dependence, $B_{eff}\sim (T_{TB}-T)^{2}$ as predicted by the recent coarse-grained elastic theory. Our results show that the structural rheology of N\textsubscript{TB} is strikingly similar to that of the usual smectic LCs although the temperature dependence of $B_{eff}$ is much faster than smectic LCs as predicted by the coarse-grained models.