锂氧电池催化阴极研究进展

Wen Wang, Simin Wang, Longhai Zhang, Sijiang Hu, X. Xiong, Tengfei Zhou, Chaofeng Zhang
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引用次数: 0

摘要

锂氧电池是最有前途的电化学储能系统之一,由于其比锂离子电池更高的能量密度,在过去几年中引起了极大的关注。锂氧电池储能是一种反应式储能机制,其放电和充电过程通常被称为氧还原反应(ORR)和析氧反应(OER)。因此,复杂的系统通常会产生复杂的问题,锂氧电池也面临许多问题,如放电产物(Li2O2)在阴极孔隙中过度积累,导致容量降低,循环性能不稳定等。阴极催化剂影响锂氧电池OER和ORR动力学,是决定电池电化学性能的决定性因素之一,因此阴极催化剂的设计至关重要。本文对催化正极材料进行了综述,分为碳基材料、金属及其氧化物、复合材料和其他材料四部分。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Recent Progress of Catalytic Cathodes for Lithium-oxygen Batteries
Lithium-oxygen batteries are among the most promising electrochemical energy storage systems, which have attracted significant attention in the past few years duo to its far more energy density than lithium-ion batteries. Lithium oxygen battery energy storage is a reactive storage mechanism, and the discharge and charge processes are usually called oxygen reduction reaction (ORR) and oxygen evolution reaction (OER). Consequently, complex systems usually create complex problems, lithium oxygen batteries also face many problems, such as excessive accumulation of discharge products (Li2O2) in the cathode pores, resulting in reduced capacity, unstable cycling performance and so on. Cathode catalyst, which could influence the kinetics of OER and ORR in lithium oxygen (Li-O2) battery, is one of the decisive factors to determine the electrochemical performance of the battery, so the design of cathode catalyst is vitally important. This review discusses the catalytic cathode materials, which are divided into four parts, carbon based materials, metals and metal oxides, composite materials and other materials.
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