高分子自旋交叉化合物中自旋态跃迁的时域光谱

2011 International Conference on Infrared, Millimeter, and Terahertz Waves Pub Date : 2011-12-15 DOI:10.1109/IRMMW-THZ.2011.6104784

B. Viquerat, J. Degert, M. Tondusson, J. Létard, C. Mauriac, E. Freysz

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引用次数: 1

摘要

我们测量了聚合物铁(II)自旋交叉化合物在低自旋/高自旋热滞后回路中在~ 0.6-6太赫兹频率范围内的太赫兹谱的演变。该研究证明了自旋态相变期间发生的折射率和吸收的大变化。

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Time-domain spectroscopy of spin state transition in polymeric spin crossover compounds

We have measured the evolution of the THz spectrum of polymeric iron(II) spin crossover compounds within the Low-Spin/High-Spin thermal hysteresis loop in the ∼0.6–6 THz frequency range. This study enabled to evidence the large variations of both the refractive optical index and the absorption that occur during the spin state phase transition.

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来源期刊

2011 International Conference on Infrared, Millimeter, and Terahertz Waves

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