单宁酸与Fe(II)和Co(II)固体化合物的表征和热行为

C. R. C. Brito, Adriana Cardoso, F. Caires, A. B. Siqueira
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引用次数: 10

摘要

由于单宁酸的许多应用,多年来人们对它进行了大量的研究。它可用于水处理,食品添加剂,制药应用和冶金工业。单宁酸用途的多样性是由于其结构中含有大量的酚基。为了更好地了解单宁酸的用途,研究了单宁酸与金属之间的行为。用不同摩尔比M:L(1:1, 2:1, 3:1, 4:1, 5:1, 6:1, 7:1)和pH(3,5,8)的混合物制备了固态M-L,其中M代表二价金属(Co, Fe), L代表单宁酸。同时用热重法和差热分析(TG - DTA)、TG- dsc、FTIR和红外光谱对这些化合物的热行为进行了表征和研究。结果揭示了分离化合物的组成、脱水、相互作用M-L和热分解等方面的信息。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Characterization and thermal behaviour of tannic acid compounds with Fe(II) and Co(II) in solid state
Tannic acid has been  much insvestigated over the years due to many applications. It can be used in water treatment, in food additive, in pharmaceutical applications and in metallurgical industries. The great variety of the tannic acid`s use is due to the numerous phenol groups in its structure. The behavior between tannic acid and metals was studied for better understanding of its use. Solid state M-L, where M represents bivalent metals (Co, Fe) and L is tannic acid, were prepared by mixture in different molar ratios M:L (1:1, 2:1, 3:1, 4:1, 5:1, 6:1, 7:1) and at pH (3, 5, 8). Simultaneous thermogravimetry and differential thermal analysis (TG - DTA), TG-DSC coupled to FTIR and infrared spectroscopy were used to characterize and to study the thermal behaviour of these compounds. The results led to information about the composition, dehydration, interaction M-L and thermal decomposition of the isolated compounds.
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