{"title":"环状有机磷化合物。第十二部分。在空间控制下酰基化中2-苯甲氧基-5,5-二甲基-2-氧基-1,3,2-二磷磷胺的使用","authors":"R. Edmundson, C. Forth, T. Moran","doi":"10.1039/J39710002452","DOIUrl":null,"url":null,"abstract":"The synthesis and benzoylating activity of 2-benzoyloxy-5,5-dimethyl-2-oxo-1,3,2-dioxaphosphorinan are described. The compound reacts selectively with the less hindered amino-group of 1,4-diamino-2,6-dibromo-benzene to give 4′-amino-3′,5′-dibromobenzanilide; benzoyl chloride attacks both amino-groups.","PeriodicalId":17245,"journal":{"name":"Journal of The Chemical Society C: Organic","volume":"164 1","pages":"2452-2453"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Cyclic organophosphorus compounds. Part XII. Use of 2-benzoyloxy-5,5-dimethyl-2-oxo-1,3,2-dioxaphosphorinan under steric control in acylations\",\"authors\":\"R. Edmundson, C. Forth, T. Moran\",\"doi\":\"10.1039/J39710002452\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The synthesis and benzoylating activity of 2-benzoyloxy-5,5-dimethyl-2-oxo-1,3,2-dioxaphosphorinan are described. The compound reacts selectively with the less hindered amino-group of 1,4-diamino-2,6-dibromo-benzene to give 4′-amino-3′,5′-dibromobenzanilide; benzoyl chloride attacks both amino-groups.\",\"PeriodicalId\":17245,\"journal\":{\"name\":\"Journal of The Chemical Society C: Organic\",\"volume\":\"164 1\",\"pages\":\"2452-2453\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society C: Organic\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J39710002452\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society C: Organic","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J39710002452","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Cyclic organophosphorus compounds. Part XII. Use of 2-benzoyloxy-5,5-dimethyl-2-oxo-1,3,2-dioxaphosphorinan under steric control in acylations
The synthesis and benzoylating activity of 2-benzoyloxy-5,5-dimethyl-2-oxo-1,3,2-dioxaphosphorinan are described. The compound reacts selectively with the less hindered amino-group of 1,4-diamino-2,6-dibromo-benzene to give 4′-amino-3′,5′-dibromobenzanilide; benzoyl chloride attacks both amino-groups.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
