埃及橄榄树修剪残留物热分解动力学研究

Fatma M. Abosamra, A. Radwan, Y. El-Hadidi, M. A. Hamad, M. El –Kholy
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引用次数: 0

摘要

在200 ~ 750℃的纳米等温区对埃及橄榄树修剪残留物(OTP)进行了动力学研究。使用热重分析(TGA)技术研究了OTP的热行为,该技术测量了样品的失重率作为温度和时间的函数。热重分析结果与近似分析结果一致。研究在5、10和20℃/min的不同升温速率下进行。采用热重分析实验测量法确定了反应的动力学参数,包括反应级数和活化能。橄榄树修剪残基的活化能达到(59.162.868.9)kJ/mol。回归模型的平方根系数分别为(0.9859,0.9534,0.9631)。所获得的动力学数据可以为更好和完整地描述热解过程提供更有用的信息,并澄清这种农业残留物的气化可行性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Kinetics of Thermal Decomposition of Egyptian Olive Tree Pruning Residues
A kinetic study for the Egyptian olive tree pruning residues (OTP) was performed in a nano isothermal area and the temperature ranged from 200 to 750 C. The thermal behavior of OTP has been studied using a technique called (thermogravimetric analysis TGA), which measures the sample's weight loss rate as a function of temperature and time. The results of TGA showed the same results as those conducted in the proximate analysis. The study was conducted at various heating rates of 5,10 and 20 C/min. The TGA experiment measurement has been used to determine the kinetic parameters, including the order of reaction and activation energy. Olive tree pruning residues in this study reached the activation energy of (59.162.868.9) kJ/mol. A regression model square root coefficient of (0.9859, 0.9534, 0.9631) was obtained. The kinetic data obtained may provide more useful information for a better and complete description of the pyrolysis process and clarify the availability to gasify this agricultural residue.
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