F. Leitzke, A. Wegner, C. Porcher, N. Vieira, J. Berndt, S. Klemme, R. Conceição
{"title":"硼酸钠熔合玻璃中全岩微量元素的LA-ICP-MS分析","authors":"F. Leitzke, A. Wegner, C. Porcher, N. Vieira, J. Berndt, S. Klemme, R. Conceição","doi":"10.1590/2317-4889202120200057","DOIUrl":null,"url":null,"abstract":"Trace elements provide crucial information about the origin and evolution of the Earth. One common issue regarding their analyses is the reduced analyte recovery during hot plate acid digestion for some geological samples. To overcome this, alkali fluxes (e.g., Lithium borate) have been used to produce an homogeneous synthetic glass that can be used then for both X-ray fluorescence (XRF) and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). In this sense, we developed a method for LA-ICP-MS whole rock trace element analyses in glasses prepared by mixing high-purity sodium tetraborate and rock powders at high-temperature. We selected six international reference materials including peridotite ( JP-1), basalt (BRP-1), kimberlite (SARM-39), pyroxenite (NIM-P), diorite (DR-N) and andesite ( JA-1). Glasses were produced in a fully automatic fusion machine with step heating. Run products analyses were carried out on a Thermo® Element2 SF-ICP-MS coupled to a New Wave Research® Nd:YAG (213 nm) laser ablation system and on a Thermo® Element XR ICP-MS coupled to an Analyte G2 (193 nm) LA system. Results show that glasses are homogeneous and there is good agreement (generally > 90%) between our data and literature values for most trace elements, including large ion lithophile elements (LILE), high-field strength elements (HFSE) and rare-earth elements (REE).","PeriodicalId":9221,"journal":{"name":"Brazilian Journal of Geology","volume":"38 1","pages":""},"PeriodicalIF":1.3000,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Whole-rock trace element analyses via LA-ICP-MS in glasses produced by sodium borate flux fusion\",\"authors\":\"F. Leitzke, A. Wegner, C. Porcher, N. Vieira, J. Berndt, S. Klemme, R. Conceição\",\"doi\":\"10.1590/2317-4889202120200057\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Trace elements provide crucial information about the origin and evolution of the Earth. One common issue regarding their analyses is the reduced analyte recovery during hot plate acid digestion for some geological samples. To overcome this, alkali fluxes (e.g., Lithium borate) have been used to produce an homogeneous synthetic glass that can be used then for both X-ray fluorescence (XRF) and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). In this sense, we developed a method for LA-ICP-MS whole rock trace element analyses in glasses prepared by mixing high-purity sodium tetraborate and rock powders at high-temperature. We selected six international reference materials including peridotite ( JP-1), basalt (BRP-1), kimberlite (SARM-39), pyroxenite (NIM-P), diorite (DR-N) and andesite ( JA-1). Glasses were produced in a fully automatic fusion machine with step heating. Run products analyses were carried out on a Thermo® Element2 SF-ICP-MS coupled to a New Wave Research® Nd:YAG (213 nm) laser ablation system and on a Thermo® Element XR ICP-MS coupled to an Analyte G2 (193 nm) LA system. Results show that glasses are homogeneous and there is good agreement (generally > 90%) between our data and literature values for most trace elements, including large ion lithophile elements (LILE), high-field strength elements (HFSE) and rare-earth elements (REE).\",\"PeriodicalId\":9221,\"journal\":{\"name\":\"Brazilian Journal of Geology\",\"volume\":\"38 1\",\"pages\":\"\"},\"PeriodicalIF\":1.3000,\"publicationDate\":\"2021-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Brazilian Journal of Geology\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://doi.org/10.1590/2317-4889202120200057\",\"RegionNum\":4,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"GEOSCIENCES, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Brazilian Journal of Geology","FirstCategoryId":"89","ListUrlMain":"https://doi.org/10.1590/2317-4889202120200057","RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"GEOSCIENCES, MULTIDISCIPLINARY","Score":null,"Total":0}
Whole-rock trace element analyses via LA-ICP-MS in glasses produced by sodium borate flux fusion
Trace elements provide crucial information about the origin and evolution of the Earth. One common issue regarding their analyses is the reduced analyte recovery during hot plate acid digestion for some geological samples. To overcome this, alkali fluxes (e.g., Lithium borate) have been used to produce an homogeneous synthetic glass that can be used then for both X-ray fluorescence (XRF) and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). In this sense, we developed a method for LA-ICP-MS whole rock trace element analyses in glasses prepared by mixing high-purity sodium tetraborate and rock powders at high-temperature. We selected six international reference materials including peridotite ( JP-1), basalt (BRP-1), kimberlite (SARM-39), pyroxenite (NIM-P), diorite (DR-N) and andesite ( JA-1). Glasses were produced in a fully automatic fusion machine with step heating. Run products analyses were carried out on a Thermo® Element2 SF-ICP-MS coupled to a New Wave Research® Nd:YAG (213 nm) laser ablation system and on a Thermo® Element XR ICP-MS coupled to an Analyte G2 (193 nm) LA system. Results show that glasses are homogeneous and there is good agreement (generally > 90%) between our data and literature values for most trace elements, including large ion lithophile elements (LILE), high-field strength elements (HFSE) and rare-earth elements (REE).
期刊介绍:
The Brazilian Journal of Geology (BJG) is a quarterly journal published by the Brazilian Geological Society with an electronic open access version that provides an in-ternacional medium for the publication of original scientific work of broad interest concerned with all aspects of the earth sciences in Brazil, South America, and Antarctica, in-cluding oceanic regions adjacent to these regions. The BJG publishes papers with a regional appeal and more than local significance in the fields of mineralogy, petrology, geochemistry, paleontology, sedimentology, stratigraphy, structural geology, tectonics, neotectonics, geophysics applied to geology, volcanology, metallogeny and mineral deposits, marine geology, glaciology, paleoclimatology, geochronology, biostratigraphy, engineering geology, hydrogeology, geological hazards and remote sensing, providing a niche for interdisciplinary work on regional geology and Earth history.
The BJG publishes articles (including review articles), rapid communications, articles with accelerated review processes, editorials, and discussions (brief, objective and concise comments on recent papers published in BJG with replies by authors).
Manuscripts must be written in English. Companion papers will not be accepted.