GC-ECD法测定贝宁棉区水体中有机氯农药残留

Man Gbaguidi, L. Dovonon, A. Youssao, Mickael Saizonou, R. Djibril, Y. Mohamed, H. Soclo, B. Fayomi
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引用次数: 2

摘要

尽管农药在农业中发挥着无可争议的作用,但它们的使用也对环境造成了影响。因此,为了了解农药使用对贝宁农业的影响,在贝宁北部和中部两个棉花种植区进行了雨季和旱季有机氯农药残留研究。采用气相色谱- ecd分析技术。在旱季,我们注意到滴滴涕及其代谢物(DDE和DDD)占所有有机氯农药(POCs)的36%,而环二苯醚占64%。硫丹占所有有机氯农药的57%,排在第一位,其次是滴滴涕,占17%。在雨季,这两种有机氯农药(POCs)占环二烯农药的73%,滴滴涕及其副产品的23%。硫丹排名第一,占所有有机氯农药的47%,其次是滴滴涕,占12%。在沉积物中,无论季节如何,环二苯醚首先占所有有机氯农药(POCs)的70%,其次是滴滴涕及其副产品,占30%。由于在水柱中,雨季沉积物的污染程度高于旱季(雨季所有有机氯农药(POCs)为25273 ppb,旱季为2.256 ppb),因此本研究得出北部地区的污染程度高于中部地区。有机氯农药不同分子含量之间也存在很强的相关性。这意味着,尽管“斯德哥尔摩公约”等现行法律严格禁止使用这些分子,但农民仍在这两个地区使用禁用农药。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Search of Organochlorine Pesticide Residues (Pocs) in Bodies of Water in Cotton- Growing Area of Benin by GC-ECD
Despite their incontestable services in agriculture, the use of pesticides is not without consequences on the environment. So, in an attempt to access the impacts of pesticides usage in agriculture in Benin, research of some residual organochloride pesticides have been conducted both in rainy and dry seasons in two cotton growing areas: the northern and central part of Benin. The analytical technique used is GC-ECD. During the dry season we notice that the DDT and its metabolites (DDE and DDD) represent 36% of all organochlorine pesticides (POCs) against 64 % of cyclodiens. Endosulfan comes first representing 57% of all organochlorine pesticides (POCs), then follows DDT with 17 %. During the rainy season these two types of organochlorine pesticides (POCs) represent 73% for cyclodiens and 23% for DDT and its by-products. Endosulfan comes first by representing 47% of all organochlorine pesticides (POCs) followed by DDT representing 12%. In the sediments and regardless of the season, the cyclodiens come first by representing 70% of all organochlorine pesticides (POCs) and then follows the DDT and its by-products which represent 30%. Since in the water column, the sediments are more contaminated in rainy season than in dry season (25273 ppb of all organochlorine pesticide (POCs) in rainy season against 2.256 ppb in dry season), it is derived from this study that northern areas are more contaminated than the central areas. Also a strong correlation has been established between the content of different moleculars of organochlorine pesticide (POCs). This means that the famers still use prohibited pesticides in the two areas despite existing laws like “Stockholm convention” which strictly ban the usage of those moleculars.
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