Waste Eggshell-Derived Calcium Oxide and Nanohydroxyapatite Biomaterials for the Preparation of LLDPE Polymer Nanocomposite and Their Thermomechanical Study

ABSTRACT Waste eggshells were utilized to make calcium oxide (E-CaO) and hydroxyapatite (E-HAP). E-CaO obtained by heat treatment to eggshells was utilized for the synthesis of E-HAP. Melt compounding of E-CaO/E-HAP was performed with linear low-density polyethylene (LLDPE) on a Brabender Plastograph and ground the obtained formulation for injection molding. Addition of E-CaO/E-HAP in the LLDPE significantly enhanced the flame retardant ability and thermal stability of resultant composites. In the comparative study, E-HAP nanopowder-containing polymer composite showed increment in thermal and mechanical properties than the composite prepared using E-CaO. GRAPHICAL ABSTRACT