Wojciech Domalewski, Lech Stefaniak, Graham Alan Webb
{"title":"一些2-取代n -苯基-P,P,P-三苯基磷酸-λ5-偶氮烯的13C, 31P和15N NMR研究","authors":"Wojciech Domalewski, Lech Stefaniak, Graham Alan Webb","doi":"10.1016/0584-8539(94)E0090-W","DOIUrl":null,"url":null,"abstract":"<div><p><sup>13</sup>C, <sup>31</sup>P and <sup>15</sup>N NMR data are reported for seven 2-substituted-N-phenyl-P,P,P-triphenylphospha-λ<sup>5</sup>-azenes taken at room temperature in acetone-d<sub>6</sub> solutions. Ortho substituents significantly influence <sup>13</sup>C, <sup>31</sup>P, <sup>15</sup>N chemical shifts and <sup>1</sup>J(<sup>31</sup>P<sup>15</sup>N), <sup>3</sup>J(<sup>31</sup>P<sup>13</sup>C) Couplings.</p></div>","PeriodicalId":82782,"journal":{"name":"Spectrochimica acta. Part A: Molecular spectroscopy","volume":"50 10","pages":"Pages 1799-1804"},"PeriodicalIF":0.0000,"publicationDate":"1994-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0584-8539(94)E0090-W","citationCount":"0","resultStr":"{\"title\":\"A 13C, 31P and 15N NMR investigation of some 2-substituted-N-phenyl-P,P,P-triphenylphospha-λ5-azenes\",\"authors\":\"Wojciech Domalewski, Lech Stefaniak, Graham Alan Webb\",\"doi\":\"10.1016/0584-8539(94)E0090-W\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p><sup>13</sup>C, <sup>31</sup>P and <sup>15</sup>N NMR data are reported for seven 2-substituted-N-phenyl-P,P,P-triphenylphospha-λ<sup>5</sup>-azenes taken at room temperature in acetone-d<sub>6</sub> solutions. Ortho substituents significantly influence <sup>13</sup>C, <sup>31</sup>P, <sup>15</sup>N chemical shifts and <sup>1</sup>J(<sup>31</sup>P<sup>15</sup>N), <sup>3</sup>J(<sup>31</sup>P<sup>13</sup>C) Couplings.</p></div>\",\"PeriodicalId\":82782,\"journal\":{\"name\":\"Spectrochimica acta. Part A: Molecular spectroscopy\",\"volume\":\"50 10\",\"pages\":\"Pages 1799-1804\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1994-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0584-8539(94)E0090-W\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Spectrochimica acta. Part A: Molecular spectroscopy\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0584853994E0090W\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Spectrochimica acta. Part A: Molecular spectroscopy","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0584853994E0090W","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
本文报道了7个2-取代- n -苯基-P,P,P-三苯基磷酸-λ5-偶氮在丙酮- 6溶液中室温下的13C, 31P和15N NMR数据。邻位取代基显著影响13C、31P、15N的化学位移和1J(31P15N)、3J(31P13C)的耦合。
A 13C, 31P and 15N NMR investigation of some 2-substituted-N-phenyl-P,P,P-triphenylphospha-λ5-azenes
13C, 31P and 15N NMR data are reported for seven 2-substituted-N-phenyl-P,P,P-triphenylphospha-λ5-azenes taken at room temperature in acetone-d6 solutions. Ortho substituents significantly influence 13C, 31P, 15N chemical shifts and 1J(31P15N), 3J(31P13C) Couplings.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
