基于热力学fedamo的hea (Fe-Ni-Cx (X=0.3-0.5)三元合金体系的calphhad计算

W. U. Shah, D. Khan, Haiqing Yin
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引用次数: 0

摘要

本文对高熵合金Fe-Ni-Cx (x=0.3 ~ 0.5)的基本热性能进行了热力学分析和计算。利用FEDAT数据库和calphhad方法对该系统进行了热计算。在Fe-Ni-C三元合金体系中,相互作用的评价在0.04070 J/m2时达到最大值。FCC_A1相是Fe- Ni-Cx (x=0.3 ~ 0.5)三元合金体系中摩尔体积最大的相。随着密度和表观热容的增加,FCC_A1相具有奥氏体配位。温度变化导致复合相在要求的水平上消失。体系的最高表观热容为0.39269 j/mol。相的密度趋于恒定,表明存在罕见的耐温相。由于相的性质和稳定性,相密度的波动随温度的变化而变化。界面能最高的基心立方结构具有较好的磁性能。该合金表现出较好的磁体配位和热力学性能增强,可供进一步分析。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Thermo-mechanical fedamo based calculations of hea (Fe-Ni-Cx (X=0.3-0.5) ternary alloys system using Calphad method
The given research shows the thermodynamic analysis and calculation of the basic thermal properties of the high entropy alloy Fe-Ni-Cx (x=0.3-0.5) of concentration. The system is investigated through Thermo-calc package with FEDAT databases and Calphad method. The evaluation of interactions is found maximum at 0.04070 J/m2 in the Fe-Ni-C ternary alloy system. The FCC_A1 phase is found the phase associated with highest molar volume in the Fe- Ni-Cx (x=0.3-0.5) ternary alloy system. The phase FCC_A1 is having austenite coordination with increasing density and apparent heat capacity. The temperature variation results the composite phases to be disappears with required level. The system is found highest apparent heat capacity 0.39269 j/mol. The density of phases becomes constant and it indicates the rare temperature withstanding phases. The fluctuations in the density of phases are changing with temperature as a result of phase’s nature and stability. The better magnetic properties are found for Basic centered cubic structure with highest interfacial energy. The alloy shows better magnet ic coordination and thermodynamic properties enhancement for further analysis.
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来源期刊
Kuwait Journal of Science & Engineering
Kuwait Journal of Science & Engineering MULTIDISCIPLINARY SCIENCES-
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