助表面活性剂对油包水乳液中co2吸收的影响

I. Dali, K. Kamarudin
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引用次数: 8

摘要

当涉及到燃料的能源使用时,二氧化碳是环境中的主要问题之一,即使燃料来自天然气。除了危害环境,二氧化碳还会影响天然气本身的热值。二氧化碳作为污染物的存在对石油和天然气行业来说是一个麻烦,因为它能够在管道中形成腐蚀,因此清除二氧化碳对该行业至关重要。在乳剂中吸收二氧化碳将是防止腐蚀的有效方法。研究了以山梨糖油酸酯(SPAN 80)为表面活性剂的1,2-二油基- n-甘油-3-磷酸胆碱(DOPC)与山梨糖油酸酯(sp80)互补的助表面活性剂对油包水(W/O)乳液稳定性的影响。本研究还探讨了以甲基二乙醇胺(MDEA)/2-氨基-2-甲基-1-丙醇(AMP)和MDEA为水相的混合胺的使用。采用改进型转盘接触器(RDC)进行吸收,采用气相色谱法测定CO2的吸收量。对乳化液吸收二氧化碳的分析表明,不同的助表面活性剂可能改变乳化液的吸收机理。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
THE EFFECT OF COSURFACTANT IN CO2 ABSORPTION IN WATER – IN – OIL EMULSION
Carbon dioxide is one of the main concern in the environment when it comes to energy usage of fuel, even the fuel is coming from natural gas sources. Apart from endangered the environment, carbon dioxide also affects the caloric value of the natural gas itself. The presence of carbon dioxide as contaminants is a nuisance for oil and gas industry as its capability of forming corrosion in pipeline, thus its removal is vital for this industry. The absorption of carbon dioxide in emulsions would be an effective method to prevent corrosion. This study focused on the effects of cosurfactant, complementing 1,2-dioleoyl-sn-glycero-3-phosphocholine (DOPC) with surfactant which is sorbitan oleate (SPAN 80), on the stability of water-in-oil (W/O) emulsion. This study also investigates the use of blended amines which are methyldiethanolamine (MDEA)/2-amino-2-methyl-1-propanol (AMP) and MDEA as aqueous phase. A modified rotating disk contactor (RDC) was used in absorption process and gas chromatography (GC) was used to determine the amount of the CO2 absorbed. Analysis of carbon dioxide absorption through emulsion indicates that different cosurfactant may change the absorption mechanism.
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