双峰谐振器的色散和超外差EPR

George A. Rinard, Richard W. Quine, Barnard T. Ghim, Sandra S. Eaton, Gareth R. Eaton
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引用次数: 29

摘要

使用交叉环路谐振器的超外差检测允许观察具有长电子自旋弛豫时间而没有通道效应的物质,并且允许观察具有比吸收光谱更高信噪比的色散光谱。用s波段(2.9 GHz)吸收和色散光谱对γ辐照熔融sio2的缺陷中心和煤中的自由基进行了验证。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Dispersion and Superheterodyne EPR Using a Bimodal Resonator

Superheterodyne detection using a crossed-loop resonator permits observation of species with long electron-spin-relaxation times without passage effects and permits observation of dispersion spectra with higher signal-to-noise than absorption spectra. This was demonstrated with S-band (2.9 GHz) absorption and dispersion spectra for the defect centers in γ-irradiated fused SiO2and for the radicals in coal.

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