含Si-P键的磷化氢引发的主基团和过渡金属介导的磷烯烃插入反应

IF 3.8 3区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Comments on Inorganic Chemistry Pub Date : 2020-10-29 DOI:10.1080/02603594.2020.1837783

Mutasem Z. Bani-Fwaz

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引用次数: 1

摘要

摘要本文主要综述了由含有至少一个硅磷键的膦衍生的1λ3-磷酸烯烃化合物。λ3-磷酸烯烃化合物具有很高的价值，因为它们被用来形成几种含过渡金属和主族元素的磷化合物。此外，还可以由1λ3-磷酸烯烃制备出不同种类的1λ3-磷酸炔烃。磷化合物的两个家族;λ3-磷酸烯烃和λ3-磷酸炔烃在化学反应中被用作均相催化剂，因此对化学家来说变得非常重要。图形抽象

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Main Group and Transition Metal-Mediated Phosphaalkene Insertion Reactions Initiated by Phosphines Containing Si–P Bond

ABSTRACT This review article focuses on 1λ3-phosphaalkene compounds derived from phosphines containing at least one silicon-phosphorous bond. 1λ3-Phosphaalkene compounds are of high value as they are used to form several phosphorous compounds containing a transition metal and main group elements. In addition to the fact that different kinds of 1λ3-phosphaalkynes are prepared from 1λ3-phosphaalkenes. Both families of phosphorous compounds; 1λ3-phosphaalkenes and 1λ3-phosphaalkynes have become important to chemists, as they are used in preparing several phosphorous compounds to be used as homogeneous catalysts in chemical reactions. GRAPHICAL ABSTRACT

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来源期刊

Comments on Inorganic Chemistry 化学-无机化学与核化学

CiteScore

9.00

自引率

1.90%

发文量

审稿时长

>12 weeks

期刊介绍： Comments on Inorganic Chemistry is intended as a vehicle for authoritatively written critical discussions of inorganic chemistry research. We publish focused articles of any length that critique or comment upon new concepts, or which introduce new interpretations or developments of long-standing concepts. “Comments” may contain critical discussions of previously published work, or original research that critiques existing concepts or introduces novel concepts. Through the medium of “comments,” the Editors encourage authors in any area of inorganic chemistry - synthesis, structure, spectroscopy, kinetics and mechanisms, theory - to write about their interests in a manner that is both personal and pedagogical. Comments is an excellent platform for younger inorganic chemists whose research is not yet widely known to describe their work, and add to the spectrum of Comments’ author profiles, which includes many well-established inorganic chemists.