用无损技术研究古钱币的表面、元素和电化学特征

R. Ion, M. David, A. Gheboianu
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引用次数: 0

摘要

文化遗产领域是文物价值不断演变的见证,它强烈地影响着我们作为人的认同感和行为。为了保护这些考古宝藏,需要采取不同的保护和修复方法。考虑到无价之宝领域,我们的研究方向引导我们通过非破坏性技术对20世纪的金属硬币进行初步研究。通过透射光光学显微镜(OM)、波长色散x射线荧光(WDXRF)和电化学腐蚀Tafel外偏振技术对铜基硬币进行了表面表征。显微观察表明铜绿层是由于硬币成分中铜含量的存在,x射线荧光光谱技术证实了铜绿层的存在。此外,电化学测试揭示了硬币的不同化学成分的腐蚀速率不同。这项研究提供了一个广泛的古钱币概述,以保存其未来的价值。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Surface, Elemental and Electrochemical Characterizations of Ancient Coins By Non – Destructive Techniques
Abstract The cultural heritage field represents a witness to artifacts values in a continuous evolution, it strongly influences our sense of identity and our behavior as people. To protect these archaeological treasures, different conservation and restoration methods are required. Considering the field of priceless artifacts, our research direction led us to preliminary studies of metallic coins from 20th century through non–destructive techniques. Copper–based coins were subjected to the surface characterization through optical microscopy (OM) in transmitted light, elemental composition analysis using Wavelength Dispersive X-ray Fluorescence (WDXRF) and electrochemical corrosion using Tafel extrapolarization technique. The microscopic investigations showed that the patina layer is due to presence of copper content in coins composition confirmed by X-ray fluorescence spectroscopy technique. Also, the electrochemical tests disclosed different corrosion rate according to each chemical composition of coins. This study provide a broad overview of ancient coins to preserve their value in the future.
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