不同粒径氢氧化镁粉末的灭火效果

Hai-qiang Liu , Ruo-wen Zong , Siuming Lo , Yuan Hu , You-ran Zhi
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引用次数: 12

摘要

《蒙特利尔议定书》签署后,越来越多的新型材料作为哈龙的替代品得到应用。对碱金属盐和磷酸铵盐的灭火效果研究较多,但颗粒大小对灭火效果的影响研究较少。研究了一种不同粒径的新型氢氧化镁灭火剂的灭火效果。在1*1*1m的密闭空间内,采用4种不同粒径的粉末进行了室内灭火效果试验。采用扫描电镜(SEM)和热重分析(TGA)对氢氧化镁粉末的物理化学特性进行了表征。结果表明,四种粉末的灭火效率均较高,氢氧化镁的灭火效率存在5μm的阈值。粉末的形态和颗粒大小会影响效率。更大比表面积和更小粒径的粉末具有更好的灭火效果。从化学抑制作用、冷却作用和窒息作用三个方面分析了灭火和可能的灭火机理。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Fire Extinguishing Efficiency of Magnesium Hydroxide Powders under Different Particle Size

After Montreal protocol, more and more new materials have been applied as the substitutes of Halon. Much attention has been paid to fire extinguishing efficiency of alkali metal salts and ammonium phosphate salts, but the effects of particle sizes have not been studied sufficiently. The fire-extinguishing efficiency of a new kind of agent based on magnesium hydroxide of different particle size was studied in this paper. Four different size powders have been used to study their fire-suppression efficiency through laboratory scale experiments in a confine space of 1*1*1m. The physical and chemical characteristics of the magnesium hydroxide powders were characterized by scanning electron microscopy (SEM) and thermal gravity analysis (TGA). The results have exhibited that these four kinds of powders are all high efficient for the fire suppression efficiency and there is a threshold value of 5μm for the fire suppression efficiency of magnesium hydroxide. The efficiency can be affected by the morphology of powders and particle size. The powders of larger specific surface area and smaller particle size are more efficient to suppress fire. Fire extinguishing and possible fire-suppression mechanisms have also been analyzed from three aspects: chemical inhibition, cooling effect and asphyxiation effect.

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