{"title":"MgI2醚酸催化的α， β-不饱和二酯与TMSCN的高效氢化反应","authors":"Haokun Pan, Hua Li, Huijun Liu, Xingxian Zhang","doi":"10.1080/10426507.2019.1700377","DOIUrl":null,"url":null,"abstract":"Abstract A mild, efficient and highly regioselective addition of trimethylsilyl cyanide (TMSCN) to α,β-unsaturated diesters has been achieved by using MgI2 etherate as catalyst under solvent-free conditions. This protocol provides the corresponding β-cyano esters in high yields. Graphical Abstract","PeriodicalId":20043,"journal":{"name":"Phosphorus Sulfur and Silicon and The Related Elements","volume":"470 1","pages":"388 - 391"},"PeriodicalIF":0.0000,"publicationDate":"2020-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"An efficient hydrocyanation of α, β-unsaturated diesters with TMSCN catalyzed by MgI2 etherate\",\"authors\":\"Haokun Pan, Hua Li, Huijun Liu, Xingxian Zhang\",\"doi\":\"10.1080/10426507.2019.1700377\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract A mild, efficient and highly regioselective addition of trimethylsilyl cyanide (TMSCN) to α,β-unsaturated diesters has been achieved by using MgI2 etherate as catalyst under solvent-free conditions. This protocol provides the corresponding β-cyano esters in high yields. Graphical Abstract\",\"PeriodicalId\":20043,\"journal\":{\"name\":\"Phosphorus Sulfur and Silicon and The Related Elements\",\"volume\":\"470 1\",\"pages\":\"388 - 391\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2020-05-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Phosphorus Sulfur and Silicon and The Related Elements\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/10426507.2019.1700377\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Phosphorus Sulfur and Silicon and The Related Elements","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/10426507.2019.1700377","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
An efficient hydrocyanation of α, β-unsaturated diesters with TMSCN catalyzed by MgI2 etherate
Abstract A mild, efficient and highly regioselective addition of trimethylsilyl cyanide (TMSCN) to α,β-unsaturated diesters has been achieved by using MgI2 etherate as catalyst under solvent-free conditions. This protocol provides the corresponding β-cyano esters in high yields. Graphical Abstract
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