M. Azócar, H. Muñoz, P. Levín, N. Dinamarca, G. Gómez, Á. Ibáñez, M. Garland, M. Páez
{"title":"1.1.5. 具有抗炎特性配体的银(I)配合物的合成与表征","authors":"M. Azócar, H. Muñoz, P. Levín, N. Dinamarca, G. Gómez, Á. Ibáñez, M. Garland, M. Páez","doi":"10.21060/CIS.V1I1.1465","DOIUrl":null,"url":null,"abstract":"Five water soluble silver(I) complex with Ibuprofen (AgIbu), Naproxen (AgNap), Mefenamic acid (AgMef), acetyl salicylic acid(AgAsp) and salicylic acid (AgSal) were synthesized and characterized by elemental analysis, FT-IR, 1 H and 13 C NMR. Data suggest coordination of the ligand to Ag(I) through the oxygen atom of the carboxylic group. AgAsp was obtained as a mixture of AgAsp and Ag(I)-2-hydroxybenzoate (AgSal) due to decomposition by thermal and hydrolysis of acetylsalicylic acid into salicylic acid. AgSal structure was confirmed by FT-IR, NMR and X-ray diffraction. Synthesized compounds were tested toward UV-radiation (258 nm, 30 W) and compared with AgCl in order to characterize their light sensibility.","PeriodicalId":10648,"journal":{"name":"Communications in Inorganic Synthesis","volume":"456 1","pages":"19-21"},"PeriodicalIF":0.0000,"publicationDate":"2013-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"5","resultStr":"{\"title\":\"1.1.5. Synthesis and characterization of silver(I) complexes with ligands having anti-inflammatory properties\",\"authors\":\"M. Azócar, H. Muñoz, P. Levín, N. Dinamarca, G. Gómez, Á. Ibáñez, M. Garland, M. Páez\",\"doi\":\"10.21060/CIS.V1I1.1465\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Five water soluble silver(I) complex with Ibuprofen (AgIbu), Naproxen (AgNap), Mefenamic acid (AgMef), acetyl salicylic acid(AgAsp) and salicylic acid (AgSal) were synthesized and characterized by elemental analysis, FT-IR, 1 H and 13 C NMR. Data suggest coordination of the ligand to Ag(I) through the oxygen atom of the carboxylic group. AgAsp was obtained as a mixture of AgAsp and Ag(I)-2-hydroxybenzoate (AgSal) due to decomposition by thermal and hydrolysis of acetylsalicylic acid into salicylic acid. AgSal structure was confirmed by FT-IR, NMR and X-ray diffraction. Synthesized compounds were tested toward UV-radiation (258 nm, 30 W) and compared with AgCl in order to characterize their light sensibility.\",\"PeriodicalId\":10648,\"journal\":{\"name\":\"Communications in Inorganic Synthesis\",\"volume\":\"456 1\",\"pages\":\"19-21\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2013-01-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"5\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Communications in Inorganic Synthesis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.21060/CIS.V1I1.1465\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Communications in Inorganic Synthesis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.21060/CIS.V1I1.1465","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
1.1.5. Synthesis and characterization of silver(I) complexes with ligands having anti-inflammatory properties
Five water soluble silver(I) complex with Ibuprofen (AgIbu), Naproxen (AgNap), Mefenamic acid (AgMef), acetyl salicylic acid(AgAsp) and salicylic acid (AgSal) were synthesized and characterized by elemental analysis, FT-IR, 1 H and 13 C NMR. Data suggest coordination of the ligand to Ag(I) through the oxygen atom of the carboxylic group. AgAsp was obtained as a mixture of AgAsp and Ag(I)-2-hydroxybenzoate (AgSal) due to decomposition by thermal and hydrolysis of acetylsalicylic acid into salicylic acid. AgSal structure was confirmed by FT-IR, NMR and X-ray diffraction. Synthesized compounds were tested toward UV-radiation (258 nm, 30 W) and compared with AgCl in order to characterize their light sensibility.
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