W. Paxton, T. E. Özdemir, İ. Şavklıyıldız, T. Whalen, Hülya Biçer, E. K. Akdoğan, Z. Zhong, T. Tsakalakos
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Anisotropic Thermal Expansion of Zirconium Diboride: An Energy-Dispersive X-Ray Diffraction Study
Zirconium diboride (ZrB2) is an attractive material due to its thermal and electrical properties. In recent years, ZrB2 has been investigated as a superior replacement for sapphire when used as a substrate for gallium nitride devices. Like sapphire, ZrB2 has an anisotropic hexagonal structure which defines its directionally dependent properties. However, the anisotropic behavior of ZrB2 is not well understood. In this paper, we use energy-dispersive synchrotron X-ray diffraction to measure the thermal expansion of polycrystalline ZrB2 powder from 300 to 1150 K. Nine Bragg reflections are fit using Pseudo-Voigt peak profiles and used to compute the and lattice parameters using a nonlinear least-squares approximation. The temperature-dependent instantaneous thermal expansion coefficients are determined for each -axis and -axis direction and are described by the following equations: = (
期刊介绍:
Journal of Advanced Ceramics is a single-blind peer-reviewed, open access international journal published on behalf of the State Key Laboratory of New Ceramics and Fine Processing (Tsinghua University, China) and the Advanced Ceramics Division of the Chinese Ceramic Society.
Journal of Advanced Ceramics provides a forum for publishing original research papers, rapid communications, and commissioned reviews relating to advanced ceramic materials in the forms of particulates, dense or porous bodies, thin/thick films or coatings and laminated, graded and composite structures.