纳米氧化锌对混合基聚酰胺-6-乙烷基膜气体渗透的影响

IF 1.2 Q4 NANOSCIENCE & NANOTECHNOLOGY
M. Sheikh, M. Asghari, M. Afsari
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引用次数: 10

摘要

谢赫M, Asghari M, Afsari M.纳米氧化锌对混合基聚酰胺-6-b-环氧乙烷膜气体渗透的影响。Int。J.纳米尺寸。, 2017;摘要以乙醇/水为溶剂,采用溶剂铸造法制备了聚(酰胺-6-b-环氧乙烷)/氧化锌(PEBA/ZnO)混合基膜。将ZnO在膜中的浓度设定为0.1 wt.%,并用AFM和FTIR对合成的膜进行了表征。在4 ~ 12 bar的环境温度和压力范围内,研究了ZnO纳米颗粒对膜的CO2、CH4和N2渗透率以及CO2/N2和CO2/CH4选择性的影响。结果表明,随着压力的增加,纳米复合膜的CO2渗透率增加了158%,从54.08 barer (4 bar)增加到139.59 barer (12 bar)。此外,纳米复合膜的CO2渗透率高于纯聚合物膜。因此,PEBA/ZnO纳米复合膜在CO2/N2和CO2/CH4分离方面具有广阔的应用前景。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of nano Zinc Oxide on gas permeation through mixed matrix poly (Amide-6-b-Ethylene Oxide)-based membranes
* Corresponding Author Email: asghari@kashanu.ac.ir How to cite this article Sheikh M, Asghari M, Afsari M. Effect of nano Zinc Oxide on gas permeation through mixed matrix poly (Amide-6-b-Ethylene Oxide)-based membranes. Int. J. Nano Dimens., 2017; 8(1): 31-39, DOI: 10.22034/ijnd.2017.24374 Abstract Poly (amide-6-b-ethylene oxide)/zinc oxide (PEBA/ZnO) mixed matrix membranes were fabricated using ethanol/water as solvent by solvent casting method. The concentration of ZnO in membrane was set to 0.1 wt.% and the synthesized membranes were characterized by AFM and FTIR. Effects of ZnO nanoparticle on CO2, CH4 and N2 permeabilities, and CO2/N2 and CO2/CH4 selectivities of the membranes were investigated at the ambient temperature and pressure range of 4–12 bar. The results revealed that the CO2 permeability of the nano-composite membrane increased 158 % with pressure, from 54.08 barrer (at 4 bar) to 139.59 barrer (at 12 bar). Furthermore, CO2 permeability for the nano-composite membrane was higher than neat polymeric membrane. The PEBA/ZnO nano-composite membranes thus provide a promising potential for CO2/N2 and CO2/CH4 separation.
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来源期刊
international journal of nano dimension
international journal of nano dimension NANOSCIENCE & NANOTECHNOLOGY-
CiteScore
2.80
自引率
20.00%
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