选矿对Getso高岭土性能的影响

N. Salahudeen, A. Mukhtar
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摘要

摘要粘土矿物在其原始形式中含有许多固有的杂质,这使得它们不适合大多数工业应用。为了克服这一问题,实现粘土矿物的增值,选矿工艺是不可缺少的解决方案。本研究调查了湿法选矿工艺对尼日利亚卡诺州Getso村当地粘土开采特性的影响。利用x射线衍射(XRD)分析仪对粘土进行了矿物学表征。利用x射线荧光分析仪对粘土进行了化学表征。用pH计对粘土进行了理化表征,用密度瓶对粘土进行了密度分析。对Getso粘土的XRD分析表明,其高岭石含量为8wt %,石英含量为51%。湿法选矿可使高岭石含量提高53%,石英杂质减少47%。XRF分析表明,格特索粘土原料硅铝比为1.55,选矿后硅铝比降至1.49。粘土的理化性质表明,格特索粘土为中性,原料粘土和选矿粘土的平均pH值分别为7.5和7.3。原料粘土比重为2.24,选矿粘土比重为2.04。该选矿工艺是有效的,高岭石含量大幅增加,从原料到选矿粘土的杂质含量均有合理的降低。石榴石含量完全还原为零,石英、斜长石和正长石含量分别还原24%、9%和13%。在沸石材料的合成中,得到的粘土可作为生产白陶器、高档陶瓷的良好原料。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of Beneficiation on the Characterization of Getso Kaolin
Abstract In their raw forms, clay minerals are found with a number of inherent impurities which make them unsuitable for most industrial applications. In order to overcome this problem and add value to clay minerals, beneficiation process is an indispensable solution. This study investigates effect of wet beneficiation process on the characteristics of a local clay mined from Getso village of Kano State, Nigeria. Mineralogical characterization of the clay was carried out using X-ray diffraction (XRD) analyzer. Chemical characterization of the clay was carried out using X-ray fluorescence analyzer. Physicochemical characterization of the clay was carried out using pH meter and density analysis conducted using density bottle. XRD analysis of Getso clay showed that the raw clay had 8 wt% kaolinite and 51% quartz. Wet beneficiation resulted into 53% improvement of the kaolinite content and 47% reduction of quartz impurity. The XRF analysis has shown that silica-alumina ratio of the raw Getso clay was 1.55 and this reduced to 1.49 after beneficiation. The physicochemical characterization of the clay has shown that Getso clay is neutral, the raw clay and beneficiated clay had average pH values of 7.5 and 7.3, respectively. Specific gravity values of the raw and beneficiated clay were 2.24 and 2.04, respectively. The beneficiation process had been effective as substantial increase in kaolinte content was observed and a reasonable decrese in the impurity contents was observed from the raw to the beneficiated clay. The Garnet content was completely reduced to zero while quartz, clinochlore and orthoclase were reduced by 24%, 9% and 13% respectively. The clay obtained after the beneficiation be serve as good raw material for production of whitewares, high grade ceramics in synthesis of zeolitic materials.
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