polyoxzoline基于脂肪

M. Beck, Paul Birnbrich, U. Eicken, H. Fischer, William E. Fristad, Brigitte Hase, H. Krause
{"title":"polyoxzoline基于脂肪","authors":"M. Beck, Paul Birnbrich, U. Eicken, H. Fischer, William E. Fristad, Brigitte Hase, H. Krause","doi":"10.1002/APMC.1994.052230116","DOIUrl":null,"url":null,"abstract":"A new, economic techniques was developed for the production of 2-alkyl-2-oxazolines with saturated, unsaturated or OH-functionalized alkylrests. In the process the fatty acids are changed into polymerizable monomers. The cationic polymerization of fattyalkyl-2-oxazolines was investigated in unpolar solvents and in bulk. It reacts in a living mechanism. The polymerization is remarkable inert against impurities like water or ethanolamide. A reaction enthalpy of ΔH= 85,9 kJ/mol was found for the bulk polymerization of 2-pentadecyl-2-oxazoline","PeriodicalId":7808,"journal":{"name":"Angewandte Makromolekulare Chemie","volume":"28 1","pages":"217-233"},"PeriodicalIF":0.0000,"publicationDate":"1994-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"38","resultStr":"{\"title\":\"Polyoxazoline auf fettchemischer Basis\",\"authors\":\"M. Beck, Paul Birnbrich, U. Eicken, H. Fischer, William E. Fristad, Brigitte Hase, H. Krause\",\"doi\":\"10.1002/APMC.1994.052230116\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A new, economic techniques was developed for the production of 2-alkyl-2-oxazolines with saturated, unsaturated or OH-functionalized alkylrests. In the process the fatty acids are changed into polymerizable monomers. The cationic polymerization of fattyalkyl-2-oxazolines was investigated in unpolar solvents and in bulk. It reacts in a living mechanism. The polymerization is remarkable inert against impurities like water or ethanolamide. A reaction enthalpy of ΔH= 85,9 kJ/mol was found for the bulk polymerization of 2-pentadecyl-2-oxazoline\",\"PeriodicalId\":7808,\"journal\":{\"name\":\"Angewandte Makromolekulare Chemie\",\"volume\":\"28 1\",\"pages\":\"217-233\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1994-12-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"38\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Angewandte Makromolekulare Chemie\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1002/APMC.1994.052230116\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Angewandte Makromolekulare Chemie","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/APMC.1994.052230116","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 38

摘要

开发了一种以饱和、不饱和或oh功能化烷基酯为原料生产2-烷基-2-恶唑啉的经济新工艺。在此过程中,脂肪酸被转化为可聚合的单体。研究了脂肪烷基-2-恶唑啉在非极性溶剂和散装溶剂下的阳离子聚合反应。它以一种有生命的机制起作用。聚合体对水或乙醇酰胺等杂质具有显著的惰性。2-十六烷基-2-恶唑啉本体聚合的反应焓为ΔH= 85,9 kJ/mol
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Polyoxazoline auf fettchemischer Basis
A new, economic techniques was developed for the production of 2-alkyl-2-oxazolines with saturated, unsaturated or OH-functionalized alkylrests. In the process the fatty acids are changed into polymerizable monomers. The cationic polymerization of fattyalkyl-2-oxazolines was investigated in unpolar solvents and in bulk. It reacts in a living mechanism. The polymerization is remarkable inert against impurities like water or ethanolamide. A reaction enthalpy of ΔH= 85,9 kJ/mol was found for the bulk polymerization of 2-pentadecyl-2-oxazoline
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信