{"title":"从声学和热力学参数在303K和2mhz频率下研究二元液体混合物中的分子相互作用","authors":"S. V. K. A. G. R. B. S V Kumbhare and G R Bedare","doi":"10.29369/ijrbat.2023.02.1.0055","DOIUrl":null,"url":null,"abstract":"The ultrasonic velocity, density and viscosity at 303K have been measured in the binary systems of acrylonitrile with 1, 4-Dioxane. From the experimental data, various acoustical parameters such as adiabatic compressibility (βa), intermolecular free length (Lf), specific acoustical impedance (Z), free volume (Vf), internal pressure (πi) and relaxation time (τ) were calculated. It has been observed that, weak dispersive type intermolecular interactions are confirmed in the systems investigated. Dipole inducement is found to be more predominant in the system. The results are interpreted in terms of molecular interaction between the components of the mixture.","PeriodicalId":14232,"journal":{"name":"International Journal of Researches in Biosciences and Agriculture Technology","volume":"151 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"STUDY OF MOLECULAR INTERACTIONS IN THE BINARY LIQUID MIXTURES FROM ACOUSTIC AND THERMODYNAMIC PARAMETERS AT 303K AND 2 MHz FREQUENCY\",\"authors\":\"S. V. K. A. G. R. B. S V Kumbhare and G R Bedare\",\"doi\":\"10.29369/ijrbat.2023.02.1.0055\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The ultrasonic velocity, density and viscosity at 303K have been measured in the binary systems of acrylonitrile with 1, 4-Dioxane. From the experimental data, various acoustical parameters such as adiabatic compressibility (βa), intermolecular free length (Lf), specific acoustical impedance (Z), free volume (Vf), internal pressure (πi) and relaxation time (τ) were calculated. It has been observed that, weak dispersive type intermolecular interactions are confirmed in the systems investigated. Dipole inducement is found to be more predominant in the system. The results are interpreted in terms of molecular interaction between the components of the mixture.\",\"PeriodicalId\":14232,\"journal\":{\"name\":\"International Journal of Researches in Biosciences and Agriculture Technology\",\"volume\":\"151 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Researches in Biosciences and Agriculture Technology\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.29369/ijrbat.2023.02.1.0055\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Researches in Biosciences and Agriculture Technology","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.29369/ijrbat.2023.02.1.0055","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
STUDY OF MOLECULAR INTERACTIONS IN THE BINARY LIQUID MIXTURES FROM ACOUSTIC AND THERMODYNAMIC PARAMETERS AT 303K AND 2 MHz FREQUENCY
The ultrasonic velocity, density and viscosity at 303K have been measured in the binary systems of acrylonitrile with 1, 4-Dioxane. From the experimental data, various acoustical parameters such as adiabatic compressibility (βa), intermolecular free length (Lf), specific acoustical impedance (Z), free volume (Vf), internal pressure (πi) and relaxation time (τ) were calculated. It has been observed that, weak dispersive type intermolecular interactions are confirmed in the systems investigated. Dipole inducement is found to be more predominant in the system. The results are interpreted in terms of molecular interaction between the components of the mixture.
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