J.Lawrence Hencher, Masood Khan, Farouq F. Said, Dennis G. Tuck
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Electrochemical preparation and structure of an unusual zinc(II) thiolato anionic cluster
The electrochemical oxidation of anodic zinc into a solution of PhSH + Et3N in CH3CN yields *Et3NH)2[Zn4(SPh)10]. The structure, as determined by X-ray crystallography, shows that the anion is a novel cluster based on a tetrahedral Zn4S10 kernel.
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