光电器件用掺Er3+硼酸盐玻璃蓝色发光二极管

M. Farag, K. Abd-Allah, G. Turky, M. El-Okr, W. Abu-raia, A. Saeed
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引用次数: 1

摘要

摘要制备了一种Er3+离子蓝色发射器,并将其掺杂在化学成分为30B2O3-30Bi2O3-20Li2O-10BaO-10PbO的主体玻璃中,用于光电子器件。研究了Er2O3的浓度分别为0.5、1、2和4 mol%,以研究Er3+离子对主体玻璃结构、热学和光致发光性能的影响。用x射线衍射图对所制备的玻璃进行了物相检测,结果表明该玻璃具有非晶性。通过XRD谱图、密度和密度参数以及FTIR光谱的变化,广泛研究了Er3+离子对所考虑的主体玻璃网络结构性能的影响。热方面,所考虑的玻璃具有高热稳定性和高玻璃成形性。光学上,光学带隙范围在2.18和2.56 eV之间,表明所考虑的玻璃具有半导体性质。在540 nm激发波长下,450、462和486 nm处有3个蓝色波段,412和427 nm处有2个紫色波段。通过CIE 1931色度图进行色度分析表明,所生产的玻璃有较强的蓝光发射。所考虑的玻璃的蓝光纯度在90.887和92.324 %之间。因此,所考虑的玻璃具有合适的特性,使其成为光电子器件中蓝色发光二极管的良好选择。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Blue light-emitting diode of Er3+-doped borate glass for optoelectronics devices
Abstract A blue emitter of Er3+ ions doped a host glass of a chemical composition 30B2O3–30Bi2O3–20Li2O–10BaO–10PbO was fabricated to be used in optoelectronics devices. Four proposed concentrations of Er2O3, which are 0.5, 1, 2, and 4 mol%, were suggested to study the impact of Er3+ ions on the structural, thermal, and photoluminescence properties of the considered host glass, respectively. The phase checking of the produced glasses using X-ray diffraction patterns showed the amorphicity phase formation. Impact of Er3+ ions on the structural properties of the considered host glass network was extensively studied through the occurred variations in XRD patterns, density and density-based parameters, and FTIR spectra. Thermally, the considered glasses have high thermal stability and high glass formability. Optically, the optical band gap, which ranged between 2.18 and 2.56 eV, signifies that the considered glasses have a semiconducting nature. Under 540 nm excitation wavelength, three bands were emitted in the blue region at 450, 462, and 486 nm and two in the violet region at 412 and 427 nm. Chromaticity analysis through CIE 1931 chromaticity diagram showed a strong blue light emission from the produced glasses. The blue light color purity of the considered glasses ranged between 90.887 and 92.324 %. Hence, the considered glasses have suitable characteristics that make them a good choice as blue light-emitting diodes in the optoelectronics devices.
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