激光烧蚀参数对ZnO/Au纳米颗粒非线性光学性质的影响

Y. Gündoğdu, Serap Yġğġt Gezgġn
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引用次数: 0

摘要

-本研究基于激光参数,采用脉冲激光烧蚀(PLA)方法在乙醇介质中合成了II-VI族材料ZnO和贵金属Au。利用Ti:Sapphire飞秒激光系统对ZnO、Au和ZnO/Au高纯块状材料进行了激光烧蚀制备纳米颗粒的研究。用紫外-可见光谱仪记录了线性吸收光谱,并在520 ~ 540 nm波长范围内观察到表面等离子体共振。采用开孔和闭孔的z扫描实验系统测定了ZnO、Au和ZnO/Au纳米粒子的非线性光学性质,并计算了三阶磁化率。本文给出了在乙醇介质中制备的纳米粒子的非线性吸收系数β (~10 ~ 11 cm/W)、非线性折射系数n2 (~10 ~ 16 cm 2 /W)和三阶磁化率χ(3)、(~10 ~ 14 esu)的计算结果,所得结果与文献报道的数据基本一致。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of Laser Ablation Parameters on Nonlinear Optical Properties of ZnO/Au Nanoparticles
— In this study, ZnO as the group II-VI materials and Au noble metal synthesized by pulsed laser ablation (PLA) method in ethanol medium based on laser parameters. Laser ablation method applied on ZnO, Au and ZnO/Au high purity bulk materials to produce nanoparticles which have been carried out using Ti:Sapphire femtosecond (fs) laser system. Linear absorption spectra were recorded using Uv-Vis spectrometer and surface plasmon resonance have been observed between 520 nm and 540 nm wavelengths. The nonlinear optical properties for ZnO, Au and ZnO/Au nanoparticles have been determined by using a z-scan experimental system using an open&closed aperture results and third order susceptibilities have been calculated. The calculated results for nanoparticles produced in ethanol medium, the nonlinear absorption coefficient, β , (~10 -11 cm/W), the nonlinear refraction coefficient, n 2 (~ 10 -16 cm 2 /W) and third order susceptibilities , χ (3) , (~ 10 -14 esu) for each of ZnO, Au and ZnO/Au nanoparticles have been presented in this work and it has been concluded that the results obtained are all in agreement with data reported in literature .
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