介绍自旋和键强度在双原子氧、过氧化物和相关物质的化学反应中的影响

Patai's Chemistry of Functional Groups Pub Date : 2014-12-29 DOI:10.1002/9780470682531.PAT0860

A. Greer, A. Balaban, J. Liebman

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引用次数: 1

摘要

这一综述章讨论了有机化学中的氧和过氧化物。描述了许多类型的氧，包括离子、自由基、双自由基和两性离子;这类物质的例子有超氧阴离子(O2⋅−)、双氧基阳离子(O2⋅+)、臭氧(O3)、氧低聚物(Ox)和氧的最低激发单重态(1Δ)。提供了对无环过氧化物和环过氧化物(例如，1,2 -二氧乙烷、1,2,3-三氧烷和1,4-内过氧化物)的分析。还提供了等电子杂原子结构和其他类似物，以帮助指导对过氧化氢和其他含氧物质稳定性的因素的思考。关键词:氢过氧化物和聚过氧化物;亚甲基和硫类;氧物种;过氧化物;激进分子

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An Introduction to the Consequences of Spin and Bond Strength in the Chemistry of Diatomic Oxygen, Peroxides, and Related Species

This review chapter discusses oxygen and peroxides in organic chemistry. Numerous types of oxygen species are described including ions, radicals, biradicals, and zwitterionic species; examples of such species are superoxide anion (O2 ⋅−), dioxygenyl cation (O2 ⋅+), ozone (O3), oxygen oligomers (Ox), and the lowest excited singlet state of oxygen (1Δ). An analysis of acyclic peroxides and cyclic peroxides (e.g., 1,2-dioxetanes,1,2,3-trioxolanes, and 1,4-endoperoxides) is provided. Isoelectronic heteroatom structures and other analogs are also provided to help guide thinking for the factors that underlie the stability of peroxide and other oxygen-containing species. Keywords: hydro- and polyperoxides; methylene and sulfur species; oxygen species; peroxides; radicals

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Patai's Chemistry of Functional Groups

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