新型双齿N'-(噻吩-2-基亚甲基)异烟碱肼配体的三氯化铁配合物:合成、x射线结构、光谱表征和电化学研究

Dame Gadiaga, A. Sy, Cheikh Ndoye, B. Traoré, Gregory Excoffier, O. Diouf, M. Gaye
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引用次数: 0

摘要

合成了(E)- n′-(噻吩-2-基亚甲基)异烟碱肼(HL)腙的Fe(III)配合物,并通过元素分析、非水介质电导率、FT-IR和电子能谱、室温磁测、电化学研究和x射线衍射结构测定对其进行了表征。在配合物中,配体以中性双齿形式作用,通过羰基氧和亚甲基氮进行配位。室温磁矩数据进一步证实了Fe(III)配合物具有高自旋八面体结构。元素分析表明,Fe(III)配合物由金属和配体组成,摩尔比为1:1。这种铁(III)络合物在DMF溶液中是一种中性电解质。电化学研究表明,决定电化学反应的是一个不可逆的电子转移过程。配合物的结构也通过x射线衍射确定,揭示了铁(III)离子周围的八面体环境。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
New Fe(III) Trichlorido Complex of a Bidentate N'-(thiophen-2-ylmethylene)isonicotinohydrazide Ligand: Synthesis, X-ray Structure, Spectral Characterization, and Electrochemistry Study
Fe(III) complex of the hydrazone  from (E)-N'-(thiophen-2-ylmethylene)isonicotinohydrazide (HL) has been synthesized and characterized by elemental analysis, electrical conductance in non-aqueous solvents, FT-IR and electronic spectroscopies, room temperature magnetic measurement, electrochemistry study as well as by X-ray diffraction structure determination. In the complex, the ligand acts in its neutral bidentate form, coordinating through the carbonyl oxygen and azomethine nitrogen. A high spin octahedral geometry assigned to the Fe(III) complex were further confirmed by room temperature magnetic moment data. Elemental analysis showed that Fe(III) complex is composed of metal and ligands in a molar ratio of 1:1. This complex of Fe(III) is a neutral electrolyte in DMF solution. The electrochemistry study shows that a one electron process determined the electrochemical reaction is governed by an electron transfer with an irreversible process.  The structure of the complex has also been determined by X-ray diffraction revealing an octahedral environment around the Fe(III) ion.
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