Xuliang Zhang, Youhong Sun, Q. Meng, Wu Jinhao, He Linkai
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引用次数: 5
摘要
为了提高金刚石的抗氧化性能,本文采用高温固相法和熔盐法在金刚石颗粒上合成了碳化硼铬(Cr-B-C)涂层。在900℃下保温2h后,金刚石表面被Cr-B-C涂层完全均匀覆盖。采用热重分析(TGA)测定了金刚石涂层Cr-B-C的抗氧化性能。结果表明,Cr-B-C涂层使金刚石在空气中保持100%质量直到1151℃,这比未涂层的金刚石(720℃)和涂层b4c的金刚石(1090℃)要好得多。cr - b -c涂层金刚石在空气中退火时,形成Cr2O3和B2O3作为氧障层,保护金刚石不被氧化。B2O3的形成具有高温流动性,有利于避免Cr2O3在空气中氧化时因体积膨胀而分层。此外,Cr2O3的存在通过减少B2O3的蒸发提供持久的保护。氧化产物(B2O3和Cr2O3)对金刚石颗粒具有互补的氧化保护作用。
Enhancement of Oxidation Resistance via Chromium Boron Carbide on Diamond Particles
To improve the oxidation resistance of diamond, chromium boron carbide (Cr–B–C) coatings were synthesized through high temperature solid state synthesis and molten salt method on diamond particles in this paper. After holding the raw material at 900 °C for 2 h, the diamond surface was completely and uniformly covered by Cr–B–C coatings. Oxidation resistance of the diamond coated Cr–B–C was determined by the thermogravimetric analysis (TGA). The results revealed that the Cr–B–C coatings held the diamonds for 100%-mass in air atmosphere until 1151 °C, which was much better than the uncoated diamonds (720 °C) and the B4C-coated diamonds (1090 °C). When Cr–B–C-coated diamond was annealed in air, Cr2O3 and B2O3 were formed as oxygen barrier layer to protect diamond from oxidation. The formation of B2O3 with high temperature fluidity was conducive to avoiding Cr2O3 delamination due to volume expansion during oxidation in air. Furthermore, the presence of Cr2O3 provided lasting protection by reducing the evaporation of B2O3. The oxidation products (B2O3 and Cr2O3) prove a complementary functional protection on diamond particles from oxidation.