生物柴油酯交换反应器的建模与控制

Tombomieye Adokiye, Akpa Jackson Gunorubon, Dagde Kenneth Kenkugile
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引用次数: 1

摘要

利用质量守恒原理,建立了连续搅拌槽反应器中用于废油(甘油三酯)酯交换制生物柴油的反应物和产物浓度分布预测的动态模型。利用7.5 Mathlab程序的ode45求解器中嵌入的四阶龙格-库塔算法对所开发的微分方程组进行了数值积分。利用动力学数据和文献资料求解模型方程,验证了模型的正确性。结果和趋势与上述文献基本一致。反应器中反应物(废油和甲醇)进口流量的(±)阶跃变化对生物柴油的生产(不稳定振荡和生物柴油输出浓度的降低)有很大影响。提出了一种基于比例积分控制器的反馈控制策略,并建立了用于控制研究的闭环模型。反应器输出(生物柴油浓度)的闭环响应表现为连续振荡响应。因此,控制器参数(比例增益Kc和积分时间)使用使用MathLab Simulink实现的“在线试错法”进行调谐,以获得最佳值,确保闭环系统的快速稳定,减少或没有振荡响应,并且没有偏移。最优控制器参数为:比例增益Kc =8.306,积分时间= 17.157 min。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Modeling and Control of a Biodiesel Transesterification Reactor
Dynamic Models for predicting the concentration profiles of the reactants and product in a Continuous Stirred Tank Reactor for the transesterification of used cooking oil (triglyceride) to biodiesel has been developed using the principle of conservation of mass. The developed system of differential equations were integrated numerically using fourth order Runge-Kutta algorithm embedded in ode 45 solver of 7.5 Mathlab program. The models were validated by solving the model equations with kinetic data and other relevant data from literatures. The results and trends were similar and in agreement with those from these literatures. Simulations of the reactor to (±) step changes in the inlet flowrates of the reactants (used cooking oil and methanol) showed great effect on biodiesel production, (instability—oscillations and reduction in output concentration of biodiesel). A feedback control strategy was developed with a Proportional-Integral (PI) Controller and a close loop model was developed for control studies. The closed loop response of the reactor output (biodiesel concentration) showed continuous oscillatory response with offset. Hence the controller parameters (proportional gain Kc and integral time ) were tuned using the “On-Line Trial and Error Method” implemented using MathLab Simulink to obtain optimum values that ensured quick stability of the closed-loop system, reduced or no oscillatory response and no offset. The optimum controller parameters were: proportional gain Kc =8.306 and integral time = 17.157 minutes.
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