纳米SiO2掺杂聚甲基丙烯酸羟乙酯(PHEMA)薄膜的力学、热及生物降解性能

Sinan Temel, E. Yaman, M. F. Gözükızıl, F. Gökmen
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引用次数: 0

摘要

本研究通过对甲基丙烯酸多羟基乙酯(PHEMA)和纳米sio2进行化学改性制备了纳米复合材料。工作范围;采用自由基引发剂和交联剂原位自由基聚合法制备了phema基纳米- sio2掺杂纳米复合水凝胶。以N,N,N′,N′-四甲基乙二胺(TEMED)为催化剂。提供了所选增强材料(SiO2)与聚合物(PHEMA)的相互作用及其应用领域结构性能的发展。研究了所得材料的化学结构、形貌、力学性能、热性能和生物降解性能。结果表明,纳米增强材料的掺入提高了膜的机械强度,改善了膜的生物降解性能,并使膜的热稳定性在纳米SiO2添加量最高时提高了4℃。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Mechanical, thermal and biodegradable behavior properties of nano SiO2 doped polyhydroxyethylmethacrylate (PHEMA) films
In this study, nanocomposite materials were prepared by chemical modification of polyhydroxy ethyl methacrylate (PHEMA) and nano-SiO2. Scope of work; PHEMA-based nano-SiO2 doped nanocomposite hydrogels were produced by in-situ free radical polymerization technique with radical initiator and crosslinker. N,N,N′,N′-tetramethyl ethylenediamine (TEMED) was used as a catalyst. The interaction of the selected reinforcement material (SiO2) with the polymer (PHEMA) and the development of its structural properties for the application area are provided. The chemical structure, morphology, mechanical, thermal and biodegradable behavior of the obtained materials were investigated. It was observed that the nano reinforcement material doped on the films increased the mechanical strength, improved the biodegradable property and increased the thermal stability by 4 °C in the film with the highest amount of nano SiO2 addition.
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