{"title":"锂电池用硼氢化物固态电解质","authors":"A. El Kharbachi, M. Sørby, M. Nygård, B. Hauback","doi":"10.1109/IRSEC48032.2019.9078280","DOIUrl":null,"url":null,"abstract":"Properties of LiBH<inf>4</inf>-LiCl-P<inf>2</inf>S<inf>5</inf> composites are studied regarding their application as solid-state electrolyte for lithium batteries. The studied materials undergo an amorphization at 60°C, accompanied with Li<sup>+</sup> conduction increase. The measured ionic conductivity for the optimized borohydride-halide-sulfide system is about ~10<sup>−3</sup> S cm<sup>−1</sup> at room temperature with low activation energies for ions migration suitable for all-solid-state battery applications near room temperature.","PeriodicalId":6671,"journal":{"name":"2019 7th International Renewable and Sustainable Energy Conference (IRSEC)","volume":"20 1","pages":"1-4"},"PeriodicalIF":0.0000,"publicationDate":"2019-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"Borohydride-based Solid-state Electrolytes for Lithium Batteries\",\"authors\":\"A. El Kharbachi, M. Sørby, M. Nygård, B. Hauback\",\"doi\":\"10.1109/IRSEC48032.2019.9078280\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Properties of LiBH<inf>4</inf>-LiCl-P<inf>2</inf>S<inf>5</inf> composites are studied regarding their application as solid-state electrolyte for lithium batteries. The studied materials undergo an amorphization at 60°C, accompanied with Li<sup>+</sup> conduction increase. The measured ionic conductivity for the optimized borohydride-halide-sulfide system is about ~10<sup>−3</sup> S cm<sup>−1</sup> at room temperature with low activation energies for ions migration suitable for all-solid-state battery applications near room temperature.\",\"PeriodicalId\":6671,\"journal\":{\"name\":\"2019 7th International Renewable and Sustainable Energy Conference (IRSEC)\",\"volume\":\"20 1\",\"pages\":\"1-4\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2019-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"2019 7th International Renewable and Sustainable Energy Conference (IRSEC)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1109/IRSEC48032.2019.9078280\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"2019 7th International Renewable and Sustainable Energy Conference (IRSEC)","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/IRSEC48032.2019.9078280","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 2
摘要
研究了LiBH4-LiCl-P2S5复合材料作为锂电池固态电解质的性能。材料在60℃时发生非晶化,同时Li+导率增加。优化后的硼氢化物-卤化物-硫化物体系在室温下的离子电导率约为~10−3 S cm−1,离子迁移活化能低,适合于室温下的全固态电池应用。
Borohydride-based Solid-state Electrolytes for Lithium Batteries
Properties of LiBH4-LiCl-P2S5 composites are studied regarding their application as solid-state electrolyte for lithium batteries. The studied materials undergo an amorphization at 60°C, accompanied with Li+ conduction increase. The measured ionic conductivity for the optimized borohydride-halide-sulfide system is about ~10−3 S cm−1 at room temperature with low activation energies for ions migration suitable for all-solid-state battery applications near room temperature.