{"title":"除其他不考虑热惯量的方法外，利用差热分析确定活化能的方法也有缺陷","authors":"J. Šesták, P. Holba","doi":"10.4172/2155-9872.1000331","DOIUrl":null,"url":null,"abstract":"The paper displays that the traditional method of kinetic evaluation of activation energies by simple portioning of the as-cast DTA curves is erroneous because is missing the impact of thermal inertia which is known since the Newton cooling law. This error is interwoven into all methods using thermal measurements. The method derivation is upgraded when using the missing terms.","PeriodicalId":14865,"journal":{"name":"Journal of analytical and bioanalytical techniques","volume":"128 6 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2016-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"Piloyan Method to Determine the Activation Energy from DTA is Defectivein Addition to other Methods which do not take into Account the ThermalInertia\",\"authors\":\"J. Šesták, P. Holba\",\"doi\":\"10.4172/2155-9872.1000331\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The paper displays that the traditional method of kinetic evaluation of activation energies by simple portioning of the as-cast DTA curves is erroneous because is missing the impact of thermal inertia which is known since the Newton cooling law. This error is interwoven into all methods using thermal measurements. The method derivation is upgraded when using the missing terms.\",\"PeriodicalId\":14865,\"journal\":{\"name\":\"Journal of analytical and bioanalytical techniques\",\"volume\":\"128 6 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2016-09-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of analytical and bioanalytical techniques\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.4172/2155-9872.1000331\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of analytical and bioanalytical techniques","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.4172/2155-9872.1000331","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Piloyan Method to Determine the Activation Energy from DTA is Defectivein Addition to other Methods which do not take into Account the ThermalInertia
The paper displays that the traditional method of kinetic evaluation of activation energies by simple portioning of the as-cast DTA curves is erroneous because is missing the impact of thermal inertia which is known since the Newton cooling law. This error is interwoven into all methods using thermal measurements. The method derivation is upgraded when using the missing terms.
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