热能设备压力部件的腐蚀-机械损伤

M. Hagarová, D. Jakubéczyová, G. Baranová
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引用次数: 0

摘要

对生物质锅炉省煤器管道的腐蚀机械损伤进行了分析。采用宏观分析、微观分析和SEM-EDX分析对钢样品进行了分析。分析结果表明,在热交换管表面流动的烟气中,高达30%的固体组分具有很强的降解作用。大量的腐蚀性成分,特别是Cl、S、Na、K和Zn,导致当工作温度降至200℃以下时,管表面形成高腐蚀性冷凝水,导致管弧底部壁厚减少80%以上,导致省煤器管壁穿孔。溢出的热水从表面释放出一层保护性腐蚀层,暴露出活性钢表面。解决不利腐蚀机械过程的方法是在保证供热设备压力部件足够的运行能力和材料寿命的同时,保证所要求的工艺参数(流动介质的工作温度和压力)、烟气的化学成分。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
CORROSIVE - MECHANICAL DAMAGE OF THE PRESSURE PARTS OF HEAT ENERGY EQUIPMENT
Corrosion mechanical damage of the economizer pipe of the biomass boiler was analysed. Macroscopic, microscopic and SEM-EDX analysis were used for the analysis of steel samples. The results of the analyses showed a strong degradation effect of a high, up to 30% solids fraction in the flowing flue gas on the surface of the heat exchange tubes. The high amount of aggressive components, in particular Cl, S, Na, K and Zn, resulted in the formation of highly aggressive condensate on the tube surface when the operating temperature dropped below 200 ° C. The result was a more than 80% reduction in the wall thickness of the tube at the bottom of its arc, leading to perforation of the economizer tube wall. Spilled heated water released a protective corrosion layer from the surface and exposed the active steel surface. The solution of the unfavourable corrosion mechanical process is to ensure the required technological parameters (operating temperature and pressure of the flowing medium), chemical composition of the flue gas while ensuring sufficient operational capability and material life of the pressure parts of the heat equipment.
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