微波辐射对分子间和分子内Friedel-Crafts酰化反应的影响

Green and Sustainable Chemistry Pub Date : 2020-01-21 DOI:10.4236/gsc.2020.101002

Y. Okada, Arisa Fujitsu

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引用次数: 0

摘要

研究了微波辐照对芳香化合物分子间和分子内Friedel-Crafts酰化反应的影响。微波辐照对分子间反应无影响，但对分子内反应有加速作用。这种增强的分子内反应活性归因于反应位点之间的高概率接近。

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Microwave Irradiation Effect on Intermolecular and Intramolecular Friedel-Crafts Acylation Reaction

The effect of microwave irradiation on the intermolecular and intramolecular Friedel-Crafts acylation of aromatic compounds was investigated. Microwave irradiation had no effect on the intermolecular reaction but had an accelerating effect on the intramolecular reaction. This enhanced intramolecular reactivity that was attributed to the high probability of close proximity between the reaction sites.

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Green and Sustainable Chemistry

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