某些氟化物体积模量的anderson - grisen参数δ和温度依赖性

R. Ramji Rao
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引用次数: 3

摘要

通过测量NaF、BaF2和CaF2晶体的三阶弹性常数,计算了NaF、BaF2和CaF2晶体的anderson - grisen参数δ。利用这些δ值,从安德森理论计算了这三种氟化物的体积模量在熔点温度范围内的温度依赖性。碱土氟化物CaF2和BaF2的体积模量随温度的变化规律相似。碱卤化物NaF的体积模量与CaF2和BaF2的体积模量的温度变化不同,这可能是由于晶体结构的不同。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Anderson-Grüneisen parameter δ and the temperature dependence of the bulk modulus of some fluorides

The Anderson-Grüneisen parameter δ has been evaluated for NaF, BaF2 and CaF2 from the measured third-order elastic constants of these crystals. Using these δ values, the temperature dependence of the bulk modulus of these three fluorides is calculated from Anderson's theory in the temperature range up to their melting points. The bulk moduli of the alkaline earth fluorides CaF2 and BaF2 have similar variation with temperature. The temperature variation of the bulk modulus of the alkali halide NaF deviates from those of CaF2 and BaF2 and this may be attributed to the difference in the crystal structures.

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