分子复合物。第十部分:8-羟基喹啉与1,3,5-三硝基苯1:1配合物的晶体和分子结构

E. Castellano, C. Prout
{"title":"分子复合物。第十部分:8-羟基喹啉与1,3,5-三硝基苯1:1配合物的晶体和分子结构","authors":"E. Castellano, C. Prout","doi":"10.1039/J19710000550","DOIUrl":null,"url":null,"abstract":"The crystal structure of the 1 : 1 complex of 8-hydroxyquinoline and 1,3,5-trinitrobenzene has been determined by three-dimensional X-ray methods. It is a plane-to-plane π–π* electron donor–acceptor complex formed from dimeric 8-hydroxyquinoline molecules as electron donors and 1,3,5-trinitrobenzene molecules as acceptors. In the stacks of alternating donor and acceptor molecules, each 1,3,5-trinitrobenzene molecule is located in the position of maximum π–π* overlap with respect to one of its neighbouring 8-hydroxyquinoline molecules and somewhat shifted from that position with respect to the other.The 8-hydroxyquinoline dimer is held together by a bifurcated hydrogen-bond system similar to that in the 8-hydroxyquinoline–chloranil complex.","PeriodicalId":17321,"journal":{"name":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"15","resultStr":"{\"title\":\"Molecular complexes. Part X. The crystal and molecular structure of the 1 : 1 complex of 8-hydroxyquinoline and 1,3,5-trinitrobenzene\",\"authors\":\"E. Castellano, C. Prout\",\"doi\":\"10.1039/J19710000550\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The crystal structure of the 1 : 1 complex of 8-hydroxyquinoline and 1,3,5-trinitrobenzene has been determined by three-dimensional X-ray methods. It is a plane-to-plane π–π* electron donor–acceptor complex formed from dimeric 8-hydroxyquinoline molecules as electron donors and 1,3,5-trinitrobenzene molecules as acceptors. In the stacks of alternating donor and acceptor molecules, each 1,3,5-trinitrobenzene molecule is located in the position of maximum π–π* overlap with respect to one of its neighbouring 8-hydroxyquinoline molecules and somewhat shifted from that position with respect to the other.The 8-hydroxyquinoline dimer is held together by a bifurcated hydrogen-bond system similar to that in the 8-hydroxyquinoline–chloranil complex.\",\"PeriodicalId\":17321,\"journal\":{\"name\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"15\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J19710000550\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J19710000550","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 15

摘要

用三维x射线法测定了8-羟基喹啉与1,3,5-三硝基苯1:1配合物的晶体结构。它是由二聚体8-羟基喹啉分子为电子供体,1,3,5-三硝基苯分子为受体形成的平面对平面π -π *电子供体-受体配合物。在供体和受体交替排列的分子堆中,每个1,3,5-三硝基苯分子相对于相邻的8-羟基喹啉分子中的一个分子位于最大π -π *重叠的位置,并且相对于另一个分子在一定程度上发生了移位。8-羟基喹啉二聚体是由一个类似于8-羟基喹啉-氯胺配合物的分叉氢键系统结合在一起的。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Molecular complexes. Part X. The crystal and molecular structure of the 1 : 1 complex of 8-hydroxyquinoline and 1,3,5-trinitrobenzene
The crystal structure of the 1 : 1 complex of 8-hydroxyquinoline and 1,3,5-trinitrobenzene has been determined by three-dimensional X-ray methods. It is a plane-to-plane π–π* electron donor–acceptor complex formed from dimeric 8-hydroxyquinoline molecules as electron donors and 1,3,5-trinitrobenzene molecules as acceptors. In the stacks of alternating donor and acceptor molecules, each 1,3,5-trinitrobenzene molecule is located in the position of maximum π–π* overlap with respect to one of its neighbouring 8-hydroxyquinoline molecules and somewhat shifted from that position with respect to the other.The 8-hydroxyquinoline dimer is held together by a bifurcated hydrogen-bond system similar to that in the 8-hydroxyquinoline–chloranil complex.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信