硅烷和锗衍生物的振动谱。第五部分:二卤基(甲基)日耳曼的红外光谱和拉曼光谱

G. K. Barker, J. Drake, R. Hemmings, B. Rapp
{"title":"硅烷和锗衍生物的振动谱。第五部分:二卤基(甲基)日耳曼的红外光谱和拉曼光谱","authors":"G. K. Barker, J. Drake, R. Hemmings, B. Rapp","doi":"10.1039/J19710003291","DOIUrl":null,"url":null,"abstract":"The i.r. and Raman spectra of the series of dihalogeno(methyl)germanes, MeGeHX2(X = F, Cl, Br, I) and their specifically deuteriated analogues, MeGeDX2, are recorded. A normal co-ordinate treatment based on a modified valence force field confirms the assignment of 17 of the 18 fundamental frequencies for each molecule. The torsional mode is not observed. The transferability of the force constants between the protonated and deuteriated species is tested.","PeriodicalId":17321,"journal":{"name":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"The vibrational spectra of silane and germane derivatives. Part V. The infrared and Raman spectra of dihalogeno(methyl)germanes\",\"authors\":\"G. K. Barker, J. Drake, R. Hemmings, B. Rapp\",\"doi\":\"10.1039/J19710003291\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The i.r. and Raman spectra of the series of dihalogeno(methyl)germanes, MeGeHX2(X = F, Cl, Br, I) and their specifically deuteriated analogues, MeGeDX2, are recorded. A normal co-ordinate treatment based on a modified valence force field confirms the assignment of 17 of the 18 fundamental frequencies for each molecule. The torsional mode is not observed. The transferability of the force constants between the protonated and deuteriated species is tested.\",\"PeriodicalId\":17321,\"journal\":{\"name\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J19710003291\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J19710003291","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 3

摘要

记录了一系列二卤代(甲基)日耳曼化合物MeGeHX2(X = F, Cl, Br, I)及其特殊氘化类似物MeGeDX2的红外光谱和拉曼光谱。基于修正价力场的标准坐标处理确认了每个分子18个基本频率中的17个。没有观察到扭转模态。测试了质子化和氘化物质之间力常数的可转移性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The vibrational spectra of silane and germane derivatives. Part V. The infrared and Raman spectra of dihalogeno(methyl)germanes
The i.r. and Raman spectra of the series of dihalogeno(methyl)germanes, MeGeHX2(X = F, Cl, Br, I) and their specifically deuteriated analogues, MeGeDX2, are recorded. A normal co-ordinate treatment based on a modified valence force field confirms the assignment of 17 of the 18 fundamental frequencies for each molecule. The torsional mode is not observed. The transferability of the force constants between the protonated and deuteriated species is tested.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信