新型ZrOCl2·8h2o催化一锅多组分合成9,10-二氢- 8h -苯并[a]杂原烯-11(12H)- 1衍生物

M. R. P. Heravi, M. Ahmadinejad, B. Masoumi, K. Nejati
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引用次数: 4

摘要

以八水合氯氧锆为催化剂,采用多组分缩合策略,通过β-萘酚、醛和环5,5-二甲基环己烷-1,3-二酮的缩合反应,建立了一种简单高效的高取代杂蒽的合成方法。本方法得到了取代的9,10-二氢- 8h -苯并[a]杂原烯-11(12H)- 1衍生物。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Novel ZrOCl2·8H2O-Catalysed One-Pot Multicomponent Synthesis of 9,10-Dihydro-8H-benzo[a]xanthen-11(12H)-one Derivatives
A simple and efficient protocol for the synthesis of highly substituted xanthenes is developed through the condensation of β-naphthol, aldehydes, and cyclic 5,5-dimethylcyclohexane-1,3-dione with zirconium oxychloride octahydrate as a catalyst via multicomponent condensation strategy. The present method gives good to excellent yields of substituted 9,10-dihydro-8H-benzo[a]xanthen-11(12H)-one derivatives.
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