{"title":"两种呋咱并[3,4-b]四唑并[1,2-d]吡嗪化合物的合成、晶体结构及热性能","authors":"刘宁, 王伯周, 李辉, 李亚南, 霍欢, 翟连杰, 来蔚鹏","doi":"10.11943/J.ISSN.1006-9941.2015.01.003","DOIUrl":null,"url":null,"abstract":"以5, 6-二氯呋咱并[3, 4- b ]吡嗪为原料, 经叠氮化、胺化两步反应分别制得7-叠氮基呋咱并[3, 4- b ]四唑并[1, 2- d ]吡嗪(AzFTP)和7-氨基呋咱并[3, 4- b ]四唑并[1, 2- d ]吡嗪(AmFTP), 并首次培养了AmFTP的单晶。X射线单晶衍射分析结果表明: AmFTP晶体属于正交晶系, P 2 1 2 1 2 1 空间群, a =0.7117(18) nm, b =0.8088(2) nm, c =1.1871(8) nm, V =0.6833(3) nm 3 , Z =4, D c =1.732 g·cm -3 , μ =0.138 mm -1 , F (000)=360, R 1 =0.0376, wR 2 =0.0988;采用差示扫描量热(DSC)、热重(TG)分析考察了目标化合物的热性能, 热分解峰温分别为149.9,186.0 ℃, 表明AmFTP比AzFTP具有更好的热稳定性。","PeriodicalId":35753,"journal":{"name":"Hanneng Cailiao/Chinese Journal of Energetic Materials","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2015-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"两种呋咱并[3,4-b]四唑并[1,2-d]吡嗪化合物的合成、晶体结构及热性能\",\"authors\":\"刘宁, 王伯周, 李辉, 李亚南, 霍欢, 翟连杰, 来蔚鹏\",\"doi\":\"10.11943/J.ISSN.1006-9941.2015.01.003\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"以5, 6-二氯呋咱并[3, 4- b ]吡嗪为原料, 经叠氮化、胺化两步反应分别制得7-叠氮基呋咱并[3, 4- b ]四唑并[1, 2- d ]吡嗪(AzFTP)和7-氨基呋咱并[3, 4- b ]四唑并[1, 2- d ]吡嗪(AmFTP), 并首次培养了AmFTP的单晶。X射线单晶衍射分析结果表明: AmFTP晶体属于正交晶系, P 2 1 2 1 2 1 空间群, a =0.7117(18) nm, b =0.8088(2) nm, c =1.1871(8) nm, V =0.6833(3) nm 3 , Z =4, D c =1.732 g·cm -3 , μ =0.138 mm -1 , F (000)=360, R 1 =0.0376, wR 2 =0.0988;采用差示扫描量热(DSC)、热重(TG)分析考察了目标化合物的热性能, 热分解峰温分别为149.9,186.0 ℃, 表明AmFTP比AzFTP具有更好的热稳定性。\",\"PeriodicalId\":35753,\"journal\":{\"name\":\"Hanneng Cailiao/Chinese Journal of Energetic Materials\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2015-01-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Hanneng Cailiao/Chinese Journal of Energetic Materials\",\"FirstCategoryId\":\"1087\",\"ListUrlMain\":\"https://doi.org/10.11943/J.ISSN.1006-9941.2015.01.003\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"Engineering\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Hanneng Cailiao/Chinese Journal of Energetic Materials","FirstCategoryId":"1087","ListUrlMain":"https://doi.org/10.11943/J.ISSN.1006-9941.2015.01.003","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"Engineering","Score":null,"Total":0}
引用次数: 0
摘要
以5, 6-二氯呋咱并[3, 4- b ]吡嗪为原料, 经叠氮化、胺化两步反应分别制得7-叠氮基呋咱并[3, 4- b ]四唑并[1, 2- d ]吡嗪(AzFTP)和7-氨基呋咱并[3, 4- b ]四唑并[1, 2- d ]吡嗪(AmFTP), 并首次培养了AmFTP的单晶。X射线单晶衍射分析结果表明: AmFTP晶体属于正交晶系, P 2 1 2 1 2 1 空间群, a =0.7117(18) nm, b =0.8088(2) nm, c =1.1871(8) nm, V =0.6833(3) nm 3 , Z =4, D c =1.732 g·cm -3 , μ =0.138 mm -1 , F (000)=360, R 1 =0.0376, wR 2 =0.0988;采用差示扫描量热(DSC)、热重(TG)分析考察了目标化合物的热性能, 热分解峰温分别为149.9,186.0 ℃, 表明AmFTP比AzFTP具有更好的热稳定性。
以5, 6-二氯呋咱并[3, 4- b ]吡嗪为原料, 经叠氮化、胺化两步反应分别制得7-叠氮基呋咱并[3, 4- b ]四唑并[1, 2- d ]吡嗪(AzFTP)和7-氨基呋咱并[3, 4- b ]四唑并[1, 2- d ]吡嗪(AmFTP), 并首次培养了AmFTP的单晶。X射线单晶衍射分析结果表明: AmFTP晶体属于正交晶系, P 2 1 2 1 2 1 空间群, a =0.7117(18) nm, b =0.8088(2) nm, c =1.1871(8) nm, V =0.6833(3) nm 3 , Z =4, D c =1.732 g·cm -3 , μ =0.138 mm -1 , F (000)=360, R 1 =0.0376, wR 2 =0.0988;采用差示扫描量热(DSC)、热重(TG)分析考察了目标化合物的热性能, 热分解峰温分别为149.9,186.0 ℃, 表明AmFTP比AzFTP具有更好的热稳定性。
期刊介绍:
Chinese Journal of Energetic Materials is a vital forum for the exchange of science and technology in energetic materials, and information on - Propellants - Explosives - Pyrotechnics - Ignition, combustion and detonation