S. Rahimzadeh, Ata Chalabi Tehran, K. Shelesh‐Nezhad
{"title":"PBT/ABS/CNT纳米复合材料的形貌、力学、热、粘弹性研究","authors":"S. Rahimzadeh, Ata Chalabi Tehran, K. Shelesh‐Nezhad","doi":"10.1080/14658011.2021.2024648","DOIUrl":null,"url":null,"abstract":"ABSTRACT Acrylonitrile-butadiene-styrene and carbon nanotubes were employed to enhance the notched impact toughness and high-temperature performance of poly(butylene terephthalate) based material. PBT/ABS/CNT nanocomposites were produced via melt-mixing process. At the next stage, the mechanical, thermal and morphological behaviour of nanocomposites were evaluated. Scanning electron microscopy showed a relatively uniform dispersion of ABS phase in the PBT host phase. The results of thermodynamic interfacial energy analysis implied that CNTs are localised in the PBT continuous phase. The existence of ABS droplets in PBT noticeably improved the notched impact toughness. The inclusion of carbon nanotubes into the PBT/ABS blend enhanced tensile, flexural and notched impact resistance. In addition, the incorporation of ABS and CNT in PBT considerably elevated the storage modulus at high temperature. The uniform dispersion of ABS phase and localisation of CNTs in the PBT continuous phase were key factors in the properties improvement.","PeriodicalId":20245,"journal":{"name":"Plastics, Rubber and Composites","volume":"10 1","pages":"160 - 170"},"PeriodicalIF":2.1000,"publicationDate":"2022-01-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Study on morphology, mechanical, thermal and viscoelastic properties of PBT/ABS/CNT nanocomposites\",\"authors\":\"S. Rahimzadeh, Ata Chalabi Tehran, K. Shelesh‐Nezhad\",\"doi\":\"10.1080/14658011.2021.2024648\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"ABSTRACT Acrylonitrile-butadiene-styrene and carbon nanotubes were employed to enhance the notched impact toughness and high-temperature performance of poly(butylene terephthalate) based material. PBT/ABS/CNT nanocomposites were produced via melt-mixing process. At the next stage, the mechanical, thermal and morphological behaviour of nanocomposites were evaluated. Scanning electron microscopy showed a relatively uniform dispersion of ABS phase in the PBT host phase. The results of thermodynamic interfacial energy analysis implied that CNTs are localised in the PBT continuous phase. The existence of ABS droplets in PBT noticeably improved the notched impact toughness. The inclusion of carbon nanotubes into the PBT/ABS blend enhanced tensile, flexural and notched impact resistance. In addition, the incorporation of ABS and CNT in PBT considerably elevated the storage modulus at high temperature. The uniform dispersion of ABS phase and localisation of CNTs in the PBT continuous phase were key factors in the properties improvement.\",\"PeriodicalId\":20245,\"journal\":{\"name\":\"Plastics, Rubber and Composites\",\"volume\":\"10 1\",\"pages\":\"160 - 170\"},\"PeriodicalIF\":2.1000,\"publicationDate\":\"2022-01-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Plastics, Rubber and Composites\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1080/14658011.2021.2024648\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, COMPOSITES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Plastics, Rubber and Composites","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1080/14658011.2021.2024648","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, COMPOSITES","Score":null,"Total":0}
Study on morphology, mechanical, thermal and viscoelastic properties of PBT/ABS/CNT nanocomposites
ABSTRACT Acrylonitrile-butadiene-styrene and carbon nanotubes were employed to enhance the notched impact toughness and high-temperature performance of poly(butylene terephthalate) based material. PBT/ABS/CNT nanocomposites were produced via melt-mixing process. At the next stage, the mechanical, thermal and morphological behaviour of nanocomposites were evaluated. Scanning electron microscopy showed a relatively uniform dispersion of ABS phase in the PBT host phase. The results of thermodynamic interfacial energy analysis implied that CNTs are localised in the PBT continuous phase. The existence of ABS droplets in PBT noticeably improved the notched impact toughness. The inclusion of carbon nanotubes into the PBT/ABS blend enhanced tensile, flexural and notched impact resistance. In addition, the incorporation of ABS and CNT in PBT considerably elevated the storage modulus at high temperature. The uniform dispersion of ABS phase and localisation of CNTs in the PBT continuous phase were key factors in the properties improvement.
期刊介绍:
Plastics, Rubber and Composites: Macromolecular Engineering provides an international forum for the publication of original, peer-reviewed research on the macromolecular engineering of polymeric and related materials and polymer matrix composites. Modern polymer processing is increasingly focused on macromolecular engineering: the manipulation of structure at the molecular scale to control properties and fitness for purpose of the final component. Intimately linked to this are the objectives of predicting properties in the context of an optimised design and of establishing robust processing routes and process control systems allowing the desired properties to be achieved reliably.